Manipulation of the coordination sphere of an FeII ion can be used to tune the balance between different catalytic pathways for oxidation (OH. versus iron‐based oxidant; see scheme). This reinvestigation of Fenton chemistry uses the iron complex shown as a mechanistic probe.
Durch Manipulation der Koordinationssphäre eines FeII‐Ions kann der Ablauf einer katalytischen Oxidation beeinflusst werden (OH. oder auf Eisen basierendes Oxidationsmittel; siehe Schema). Bei dieser Neuuntersuchung der Fenton‐Chemie diente der gezeigte Eisenkomplex als mechanistische Probe.
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