Abstract. This paper presents the preliminary results of nocturnal Aerosol Optical Depth (τa) and Angström Exponent (α) obtained from a new lunar photometer prototype, trade name Cimel CE-318U. Due to the variation of the moon's illumination inherent to the lunar cycle, the typical Langley-plot Method used in solar photometry to calibrate these instruments cannot be applied. In this paper, we propose three different methods to carry out the lunar-photometer calibration. In order to validate the results, we have selected three events which encompass seven nights and ten days under different atmospheric conditions, including several saharan dust intrusions episodes. Method#1 is introduced in this work as a modification of the usual Langley Method. This technique, called Lunar-Langley Method, requires the extraterrestrial irradiances from a lunar irradiance model, providing similar accuracies on τa to those of AERONET (±0.01–0.02). It makes comparable daytime and nighttime measurements. Method#2 consists of transferring the current calibration from a master used by sunphotometers. Its results are again within the limit of accuracy expected for the instrument. Method#3 uses an integrating sphere and the methodology proposed by Li et al. (2008) to determine sky calibration coefficients (Cj) and the instrument's solid angle field-of-view (Ω), respectively. We observe significant τa differences between Method#1 and #3 (up to 0.07), which might be attributed to the errors propagation in Method#3. The good results obtained from the comparison against a second CE-318U prototype, and against daytime data from a Precision Filter Radiometer (PFR), constitute a valuable assessment of CE-318U performance. Results of α and its spectral variation (δ α) show good agreement between daytime and nighttime, being able to identify the aerosol properties associated with each event.

Abstract. We present two years of in situ measurements of water vapour (H 2 O) and its isotopologue ratio (δD, the standardized ratio between H 2 16 O and HD 16 O), made at two remote mountain sites on Tenerife in the subtropical North Atlantic. We show that the data -if measured during night-time -are well representative for the lower/middle free troposphere. We use the measured H 2 O-δD pairs, together with dust measurements and back trajectory modelling for analysing the moisture pathways to this region. We can identify four principally different transport pathways. The air mass transport from high altitudes and high latitudes shows two different scenarios. The first scenario brings dry air masses to the stations, as the result of condensation events occurring at low temperatures. The second scenario brings humid air masses to the stations, due to cross-isentropic mixing with lower-level and more humid air during transport since last condensation (LC). The third pathway is transportation from lower latitudes and lower altitudes, whereby we can identify rain re-evaporation as an occasional source of moisture. The fourth pathway is linked to the African continent, where during summer, dry convection processes over the Sahara very effectively inject humidity from the boundary layer to higher altitudes. This so-called Saharan Air Layer (SAL) is then advected westward over the Atlantic and contributes to moisten the free troposphere. We demonstrate that the different pathways leave distinct fingerprints on the measured H 2 O-δD pairs.

Abstract. The project MUSICA (MUlti-platform remote Sensing of Isotopologues for investigating the Cycle of Atmospheric water) integrates tropospheric water vapour isotopologue remote sensing and in situ observations. This paper presents a first empirical validation of MUSICA's H 2 O and δD remote sensing products, generated from groundbased FTIR (Fourier transform infrared), spectrometer and space-based IASI (infrared atmospheric sounding interferometer) observation. The study is made in the area of the Canary Islands in the subtropical northern Atlantic. As reference we use well calibrated in situ measurements made aboard an aircraft (between 200 and 6800 m a.s.l.) by the dedicated ISOWAT instrument and on the island of Tenerife at two different altitudes (at Izaña, 2370 m a.s.l., and at Teide, 3550 m a.s.l.) by two commercial Picarro L2120-i water isotopologue analysers.The comparison to the ISOWAT profile measurements shows that the remote sensors can well capture the variations in the water vapour isotopologues, and the scatter with respect to the in situ references suggests a δD random uncertainty for the FTIR product of much better than 45 ‰ in the lower troposphere and of about 15 ‰ for the middle troposphere. For the middle tropospheric IASI δD product the study suggests a respective uncertainty of about 15 ‰. In both remote sensing data sets we find a positive δD bias of 30-70 ‰.Complementing H 2 O observations with δD data allows moisture transport studies that are not possible with H 2 O observations alone. We are able to qualitatively demonstrate the added value of the MUSICA δD remote sensing data. We document that the δD-H 2 O curves obtained from the different in situ and remote sensing data sets (ISOWAT, Picarro at Izaña and Teide, FTIR, and IASI) consistently identify two different moisture transport pathways to the subtropical north eastern Atlantic free troposphere.

Abstract. More than 2 years of columnar atmospheric aerosol measurements (2006)(2007)(2008)(2009) at the Tamanrasset site (22.79 • N, 5.53 • E, 1377 m a.s.l.), in the heart of the Sahara, are analysed. Aerosol Robotic Network (AERONET) level 2.0 data were used. The KCICLO (K is the name of a constant and ciclo means cycle in Spanish) method was applied to a part of the level 1.5 data series to improve the quality of the results. The annual variability of aerosol optical depth (AOD) and Ångström exponent (AE) has been found to be strongly linked to the convective boundary layer (CBL) thermodynamic features. The dry-cool season (autumn and winter) is characterized by a shallow CBL and very low mean turbidity (AOD ∼ 0.09 at 440 nm, AE ∼ 0.62). The wet-hot season (spring and summer) is dominated by high turbidity of coarse dust particles (AE ∼ 0.28, AOD ∼ 0.39 at 440 nm) and a deep CBL. The aerosol-type characterization shows desert mineral dust as the prevailing aerosol. Both pure Saharan dust and very clear sky conditions are observed depending on the season. However, several case studies indicate an anthropogenic fine mode contribution from the industrial areas in Libya and Algeria. The concentration weighted trajectory (CWT) source apportionment method was used to identify potential sources of air masses arriving at Tamanrasset at several heights for each season. Microphysical and optical properties and precipitable water vapour were also investigated.

Abstract.We compare the currently most precise, groundbased total O 3 measurement techniques: Brewer and FTIR. We give an overview of the similarities and the differences between the measurements and the retrieval approaches of both experiments. We compare coincident measurements performed at the Atmospheric Observatory of Izaña from 2005 to 2007 and demonstrate that, if the properties of the instruments are well characterised, the scatter between both experiments is as small as 0.5%. This is in agreement with the theoretical predictions and confirms empirically that both techniques are able to monitor total O 3 amounts with a precision of better than 0.4%. However, we found systematic differences between both techniques of around 4.5%, which we think are mainly due to discrepancies between the applied UV and infrared spectroscopic parameters.

Abstract. A comprehensive comparison of more than 70 000 synchronous 1 min aerosol optical depth (AOD) data from three Global Atmosphere Watch precision-filter radiometers (GAW-PFR), traceable to the World AOD reference, and 15 Aerosol Robotic Network Cimel radiometers (AERONET-Cimel), calibrated individually with the Langley plot technique, was performed for four common or “near” wavelengths, 380, 440, 500 and 870 nm, in the period 2005–2015. The goal of this study is to assess whether, despite the marked technical differences between both networks (AERONET, GAW-PFR) and the number of instruments used, their long-term AOD data are comparable and consistent. The percentage of data meeting the World Meteorological Organization (WMO) traceability requirements (95 % of the AOD differences of an instrument compared to the WMO standards lie within specific limits) is >92 % at 380 nm, >95 % at 440 nm and 500 nm, and 98 % at 870 nm, with the results being quite similar for both AERONET version 2 (V2) and version 3 (V3). For the data outside these limits, the contribution of calibration and differences in the calculation of the optical depth contribution due to Rayleigh scattering and O3 and NO2 absorption have a negligible impact. For AOD >0.1, a small but non-negligible percentage (∼1.9 %) of the AOD data outside the WMO limits at 380 nm can be partly assigned to the impact of dust aerosol forward scattering on the AOD calculation due to the different field of view of the instruments. Due to this effect the GAW-PFR provides AOD values, which are ∼3 % lower at 380 nm and ∼2 % lower at 500 nm compared with AERONET-Cimel. The comparison of the Ångström exponent (AE) shows that under non-pristine conditions (AOD >0.03 and AE <1) the AE differences remain <0.1. This long-term comparison shows an excellent traceability of AERONET-Cimel AOD with the World AOD reference at 440, 500 and 870 nm channels and a fairly good agreement at 380 nm, although AOD should be improved in the UV range.

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Abstract. A 37-year long-term series of monochromatic aerosol optical depth (AOD) has been recovered from solar irradiance measurements performed with the solar spectrometer Mark-I, deployed at Izaña mountain since 1976. The instrument operation is based on the method of resonant scattering, which affords wavelength absolute reference and stability (long-term stability and high precision) in comparison to other instruments based purely on interference filters. However, it has been specifically designed as a reference instrument for helioseismology, and its ability to determine AOD from transmitted and scattered monochromatic radiation at 769.9 nm inside a potassium vapour cell in the presence of a permanent magnetic field is evaluated in this paper. Particularly, the use of an exposed mirror arrangement to collect sunlight as well as the Sun–laboratory velocity dependence of the scattered component introduces some important inconveniences to overcome when we perform the instrument's calibration. We have solved this problem using a quasi-continuous Langley calibration technique and a refinement procedure to correct for calibration errors as well as for the fictitious diurnal cycle on AOD data. Our results showed similar calibration errors retrieved by means of this quasi-continuous Langley technique applied in different aerosol load events (from 0.04 to 0.3), provided aerosol concentration remains constant throughout the calibration interval. It assures the validity of this technique when it is applied in those periods with relatively high aerosol content. The comparative analysis between the recovered AOD data set from the Mark-I and collocated quasi-simultaneous data from the Cimel-AErosol RObotic NETwork (AERONET) and Precision Filter Radiometer (PFR) instruments showed an absolute mean bias &amp;leq; 0.01 in the 10- and 12-year comparison, respectively. High correlation coefficients between AERONET and Mark-I and PFR/Mark-I pairs confirmed a very good linear relationship between instruments, proving that recovered AOD data series from Mark-I can be used together with PFR and AERONET AOD data to build a long-term AOD data series at the Izaña site (1976–now), suitable for future analysis of aerosols trends and inter-annual variability. Finally, the AOD preliminary trend analysis in the 29-year period from 1984 to 2012 with Mark-I AOD revealed no significant trends.