The (56)Fe/(54)Fe of Fe-bearing phases precipitated in sedimentary environments varies by 2.5 per mil (delta(56)Fe values of +0.9 to -1. 6 per mil). In contrast, the (56)Fe/(54)Fe of Fe-bearing phases in igneous rocks from Earth and the moon does not vary measurably (delta(56)Fe = 0.0 +/- 0.3 per mil). Experiments with dissimilatory Fe-reducing bacteria of the genus Shewanella algae grown on a ferrihydrite substrate indicate that the delta(56)Fe of ferrous Fe in solution is isotopically lighter than the ferrihydrite substrate by 1.3 per mil. Therefore, the range in delta(56)Fe values of sedimentary rocks may reflect biogenic fractionation, and the isotopic composition of Fe may be used to trace the distribution of microorganisms in modern and ancient Earth.

Pure cultures of Chlorella sp. catalyzed the oxidation of soluble Mn(II) to particulate, extracellular, manganic oxides. Manganese oxidation was dependent on photosynthetic activity: no oxidation was observed in the dark when cells were grown heterotrophically on glucose, or in the light when photosystem II was inhibited by the addition of DCMU. Manganates were not formed when media were buffered below pH 8.0, suggesting that an important driving force for manganese oxidation was the high pH resulting from photosynthesis. Field studies with minielectrodes in Oneida Lake, New York, demonstrated steep gradients of 0, and pH and the presence of particulate manganic oxides associated with pelagic aggregates of the cyanobacterium Microcystis sp. The manganese oxidation reaction apparently occurs only when photosynthesizing algae are present as dense populations that can generate microenvironments of high (> 9.0) pH, either as aggregates in the pelagic zone or concentrated cell cultures in the laboratory. A large-scale transition from soluble to particulate manganese was measured in the surface waters of Oneida Lake throughout summer 1986. Removal of Mn(II) was correlated with the presence of aggregate-forming cyanobacteria that oxidize Mn(II) by the mechanism described above.

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Lake Michigan, a 58,000-km(2) freshwater inland sea, is large enough to have persistent basin-scale circulation yet small enough to enable development of approximately balanced budgets for water, energy, and elements including carbon and silicon. Introduction of nonindigenous species-whether through invasion, intentional stocking, or accidental transplantation-has transformed the lake's ecosystem function and habitat structure. Of the 79 nonindigenous species known to have established reproductive populations in the lake, only a few have brought considerable ecological pressure to bear. Four of these were chosen for this review to exemplify top-down (sea lamprey, Petromyzon marinus), middle-out (alewife, Alosa pseudoharengus), and bottom-up (the dreissenid zebra and quagga mussels, Dreissena polymorpha and Dreissena rostriformis bugensis, respectively) transformations of Lake Michigan ecology, habitability, and ultimately physical environment. Lampreys attacked and extirpated indigenous lake trout, the top predator. Alewives outcompeted native planktivorous fish and curtailed invertebrate populations. Dreissenid mussels-especially quagga mussels, which have had a much greater impact than the preceding zebra mussels-moved ecosystem metabolism basin-wide from water column to bottom dominance and engineered structures throughout the lake. Each of these non indigenous species exerted devastating effects on commercial and sport fisheries through ecosystem structure modification.

Geochronological U-Pb (LA-ICP-MS), geochemical and isotopic data from metavolcanic felsic rocks of the Canigó and Cap de Creus massifs in the Eastern Pyrenees provide evidence of an Ediacaran magmatic event lasting 30 m.y. in NE Iberia. Data also constrain the age of the Late Neoproterozoic succession in the Cap de Creus massif, where depositional ages range from 577 to 558 Ma, and in the Canigó massif, where the data (575 to 568 Ma) represent minimum ages. Geochemistry indicates that the rocks were formed in a back-arc environment and record a fragment of a long-lived subduction-related magmatic arc (620 to 520 Ma) in the active northern Gondwana margin. The homogeneity shown by all these crustal fragments along this margin suggests that the individualization of the Pyrenean basement from the Iberian Massif started later, probably during its transition from an active to a passive margin in Cambro-Ordovician times.

Variscan migmatites cropping out in the eastern Pyrenees were dated together with Late Variscan plutonic rocks. Upper Proterozoic-Lower Cambrian series were migmatized during a thermal episode that occurred in the interval 320-315 Ma coeval with the main Variscan deformation event (D 1 ). The calc-alkaline Sant Llorenç-La Jonquera pluton and the gabbro-diorite Ceret stock were emplaced during a later thermal episode synchronous with the D 2 deformation event. A tonalite located at the base of La Jonquera suite intruded into the upper crustal levels between 314 and 311 Ma. The gabbro-diorite stock was emplaced in the middle levels of the series in two magmatic pulses at 312 and 307 Ma. The thermal evolution recorded in the eastern Pyrenees can be correlated with that of neighbouring areas of NE Iberia (Pyrenees-Catalan Coastal Ranges) and SE France (Montagne Noire). The correlation suggests a NW-SE-trending zonation where the northeasternmost areas (Montagne Noire and eastern Pyrenees) would occupy relatively more internal zones of the orogen than the southwesternmost ones.