In this research work, we prepared for the first time TiO 2 nanosheets and nanobowls assembled on an arrangement of TiO 2 nanocavities, and studied their morphological, optical, and structural properties. The assembled nanostructures were synthesized by a fast two-step electrochemical anodization using fluorides and ethylene glycol. By Field Emission Scanning Electron Microscopy, we showed that these nanostructures have a morphology well organized and ordered with a homogeneous distribution. Also, other characteristics such as photoluminescence, reflectance spectra, band gap energy, and Raman spectra were studied and compared with the optical and structural properties of TiO 2 nanotubes. We found that the time of anodization is a key parameter to control the final shape of the individual elements in the nanostructure. Our results show that when nanobowls or nanosheets are self-assembled on nanocavities the morphological, optical, and structural properties change significantly in comparison to TiO 2 nanotubes. Furthermore, the emission was improved considerably and the band gap energy was modified to higher energy values. Likewise, the interference fringes are generated in the reflectance spectra by the length of the nanocavities and by the thickness of the nanobowls and the nanosheets. Finally, a reduction on the displaced the E g(1) Raman mode was observed with decreasing of the length of the nanocavities.
In this paper, we report the results of the optical and electrical properties of TiO2 nanotubes with different morphologies for gas sensing applications. Four nanomaterials of TiO2 were prepared by electrochemical anodization using four different electrolyte solutions: 0.255 wt% NH4F with 1 wt%, 3 wt%, 6 wt% and 9 wt% of deionized water in ethylene glycol. Micrographs by scanning electron microscopy (SEM) showed different morphologies caused by the variation in the water content of the solutions. Consequently, as an effect of morphology, the photoluminescence intensity in the visible spectrum was modified. By a change of the crystalline phase of TiO2 nanotubes, the oxygen vacancies increased and affected to the optical and electrical properties of TiO2 films. These films were used for detecting gas at room temperature. Hence, we studied and analyzed the relationship of the morphology, elemental composition, phase composition, band gap energy and defect states as a function of the electrical resistance change of TiO2 nanotubes to understand and improve the sensor response.
We present an alternative post-processing on a CMOS chip to release a planar microelectrode array (pMEA) integrated with its signal readout circuit, which can be used for monitoring the neuronal activity of vestibular ganglion neurons in newborn Wistar strain rats. This chip is fabricated through a 0.6 μm CMOS standard process and it has 12 pMEA through a 4 × 3 electrodes matrix. The alternative CMOS post-process includes the development of masks to protect the readout circuit and the power supply pads. A wet etching process eliminates the aluminum located on the surface of the p+-type silicon. This silicon is used as transducer for recording the neuronal activity and as interface between the readout circuit and neurons. The readout circuit is composed of an amplifier and tunable bandpass filter, which is placed on a 0.015 mm2 silicon area. The tunable bandpass filter has a bandwidth of 98 kHz and a common mode rejection ratio (CMRR) of 87 dB. These characteristics of the readout circuit are appropriate for neuronal recording applications.
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