The results of research in the use of Au grain morphological and compositional properties applied in primary Au ore exploration are presented here. Two different and independent topics are discussed: (1) morphological characteristics of Au grains from active stream sediments for use as a distance-to-source indicator; (2) compositional signature of Au grains from various deposit types for use as a discrimination tool for source type and present deposit erosion level determination. The purpose of this study is to improve and integrate these two approaches as an exploration tool for Andean covered areas. Au grain morphology for over 1500 nuggets recovered from 60 active stream sediment samples in the Coastal Cordillera of Central Chile shows morphological variations (general shape, outline, surface, primary crystal imprints, associated minerals, flatness index) characteristic of three distance ranges (0–50 m; 50–300 m; >300 m) from source. Comparison with results from other similar studies of Au morphology characteristics in different climatic and/or sedimentological environments (arid, semi-arid, wet, lateritic, fluvial, fluvio-glacial and glacial) resulted in the determination of the recommended parameters (outline, surface, associated minerals, flatness index) to be used as distance-to-source indicator, independent of the climatic and/or sedimentological environment. Au grain morphological characteristics may assist in location of target but are not indicators of source type. Study of Au composition via electron microprobe analysis of Au grain cores from epithermal, Au-rich porphyry and Au-rich porphyry Cu systems indicated Au–Ag–Cu contents to be the best discrimination tool for these different types of Au-bearing deposits. In addition, such analysis of grains recovered at different vertical levels from the Cerro Casale Au-rich porphyry provides evidence that the Au compositional signature for a single type of deposit can also aid in the determination of vertical position. This may provide an estimate of the current level of erosion and remaining potential of the source. Some limitations of the proposed techniques are: (1) Au liberated from rock fragments already distant from source would be common in cordilleran and glacial environments, although this would be a detectable feature; (2) these techniques are applicable only for coarse-Au sources; (3) estimate of erosion level of liberated Au is limited to the case here presented.

Adakite-like features are recognized in the Late Miocene ($10 Ma) porphyritic intrusions of the Los Pelambres giant porphyry copper deposit, central Chile (32°S). Located within the southern portion of the flat-slab segment (28-33°S) of the Chilean Andes, the Al-and Na-rich porphyries of Los Pelambres display distinctly higher Sr/Y ($100-300) and La N /Yb N ($25-60) ratios than contemporaneous and barren magmatic units (e.g., La Gloria pluton, Cerro Aconcagua volcanic rocks) of the same Andean magmatic belt. Strong fractionation of heavy rare earth elements (HREE), absence of Eu anomalies, high Sr/Y and Zr/Sm and low Nb/Ta ratios suggest melt extraction from a garnet-amphibolite source. The Late-Miocene adakitelike porphyritic intrusions at Los Pelambres formed closely related in time and space to the subduction of the Juan Ferna´ndez Ridge (JFR) hotspot chain along the Chilean margin. Current tectonic reconstructions reveal that, at the time of formation of the Los Pelambres rocks, a WE segment of the JFR started to subduct beneath them, producing a slowdown of a previously rapid southward migration of a NE-ridge-trench collision. These particular tectonic conditions are favorable for the origin of the Los Pelambres porphyry suite by melting of subducting young hotspot rocks under flatslab conditions. The incorporation of crustal components into the oceanic lithopheric magma source by subduction erosion is evidenced by the Sr-Nd isotope composition of the Los Pelambres rocks different from the MORB signatures of true adakites. A close relationship apparently exists between the origin of this adakite-like magmatism and the source of the mineralization in the Los Pelambres porphyry copper deposit.

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Artículo de publicación ISISupergene enrichment of Cu deposits in the Atacama Desert has played a critical role in making this the prime Cu-producing province of the world. Previously, this has been believed to have occurred exclusively over a long period from the middle Eocene to the late Miocene, which ended when climatic conditions changed from arid to hyperarid. Here, we report U-series disequilibrium ages in atacamite-bearing supergene assemblages that provide a new conceptualization on both the supergene enrichment process and the onset of extreme hyperaridity in the Atacama Desert. 230Th–234U ages of gypsum intergrown with atacamite in supergene veins from Cu deposits cluster at ~240 ka (Chuquicamata), 130 ka (Mantos Blancos, Spence), and 80 ka (Mantos de la Luna, Michilla). When coupled with previous data, these results indicate that supergene enrichment of Cu deposits did not cease after the onset of hyperaridity. We propose that supergene enrichment in the Atacama region developed in two main stages. The main phase, caused by downward circulation of meteoric waters in a semi-arid setting, was active from 45 until ~9 Ma, with a last pulse ca. 5 Ma in the southern Atacama Desert. During this phase, atacamite-bearing supergene assemblages were not preserved because atacamite requires saline water for its formation and rapidly dissolves when contacted by meteoric water. This was followed by a second stage starting at ~2–1.5 Ma and continuing until at least the late Pleistocene, when deep formation waters derived from the basement passed up through and modified the pre-existing supergene Cu oxide minerals. Atacamite has then been preserved in the prevailing hyperarid climate.FONDECYT grant no. 1070736

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