As an answer to the increasing demand for photovoltaics as a key element in the energy transition strategy of many countries—which entails land use issues, as well as concerns regarding landscape transformation, biodiversity, ecosystems and human well-being—new approaches and market segments have emerged that consider integrated perspectives. Among these, agrivoltaics is emerging as very promising for allowing benefits in the food–energy (and water) nexus. Demonstrative projects are developing worldwide, and experience with varied design solutions suitable for the scale up to commercial scale is being gathered based primarily on efficiency considerations; nevertheless, it is unquestionable that with the increase in the size, from the demonstration to the commercial scale, attention has to be paid to ecological impacts associated to specific design choices, and namely to those related to landscape transformation issues. This study reviews and analyzes the technological and spatial design options that have become available to date implementing a rigorous, comprehensive analysis based on the most updated knowledge in the field, and proposes a thorough methodology based on design and performance parameters that enable us to define the main attributes of the system from a trans-disciplinary perspective.

Reduced graphene oxide (rGO) is widely seen as the most promising route for the low-cost mass production of graphene for many applications ranging from ultrathin electrodes to structural nanocomposites. The Hummers and Marcano methods are the two most successful approaches for producing high-performance rGO, but have been criticized for producing toxic emissions. We have applied life cycle assessment methodology to evaluate the environmental impacts of both production routes for GO and rGO in the context of applications requiring bulk materials or thin coatings. We find no current obstacle to the industrial scale production of graphene arising from its environmental impact. The cumulative energy demand is found to have a cap value between 20.7 and 68.5 GJ/Kg, a relatively high value; impact in other categories (such as human toxicity or resource depletion) is lower, and materials inventory does not include critical/strategic materials other than graphite itself. Our study proposes 1 kg of graphene as functional unit, and an application-specific functional unit normalized by conductivity which show that Hummers production method is far more suitable for bulk applications of graphene, with lower embedded energy per kg of graphene production, while Marcano's production method is better suited for thin film electronic applications.

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