This work aims to evaluate the performance of anticorrosive thermoplastic coatings in cold rolled steel sheets. Two types of thermoplastic coatings were studied: polystyrene (PS) and cornstarch. These types of coatings are applied for protection against corrosion during transport and storage of steel plates after cold rolling until delivery to stamping or other processing. The good performance for these coatings is suitably standardized to ABNT NBR 5915-2: 2013 and ASTM A1008 / A1008M-2016. According to corrosion tests carried out in saline chamber, the coatings were satisfactory in different degrees of guarantee of corrosion protection on ASTM 1080 steel, in accordance with standards mentioned.
This paper explored the effect of adding organic fibers from either bamboo or sugarcane on the mechanical properties of concrete. Cylindrical and prismatic specimens were made containing 2% and 5% v/w (volume to weight) of vegetable fibers to concrete. Following 28 days of curing period, the samples were evaluated for compressive strength, tensile strength using diametric compression, tensile strength during bending and static modulus. It was discovered that all concretes produced met the minimum strength of 20 MPa recommended by NBR 6118 for structural purposes, and it was observed an increase of the compressive strength on the specimens with addition of organic fibers. Moreover, an increase in the compressive strength was observed in the specimens with fiber addition, although no significant variation of water absorption was noticed when compared with the standard concrete. In conclusion, the concrete containing 2% v/w of bamboo fibers showed better mechanical strength and static modulus of elasticity when compared to both concrete with sugar cane fibers addition and the concrete without any additional fibers.
The formation and characterization of poly(itaconic acid)/N-methylol acrylamide/poly(ethylene glycol) (PIA/NMA/PEG) complexes through in situ polymerization of itaconic acid on poly(ethylene glycol) was investigated. FTIR indicated that PEG crystallization was hindered by complex formation. The decrease in the crystallinity of PEG was also observed by DSC and indicated that the mobility of some PEG segments was inhibited by the presence of the polyacid. According to the swelling experiments, complexes proved to be suitable for use as excipient in the preparation of drug delivery systems responsive to pH changing. DMA was used to estimate the crosslink densities and the results were found to be in good agreement with the swelling results. Further, the adhesion strength of the synthesized polymers was used as preliminary evaluation of their potential of mucoadhesion. The results indicated that the adhesion performance is related to the presence of NMA. Drugs which suffer degradation in stomach pH, such as proteins and enzymes are potential candidates to be included in the systems based on PIA/ NMA/PEG to pass through the stomach (pH near to 1.2-3.5). Upon reaching the initial portion of the small intestine (pH [5.5), the polymer will swell and release the active substance via diffusion and/or erosion of the matrix.
ResumoEste trabalho objetiva o estudo da influência da adição de fibras vegetais de bambu e cana-deaçúcar nas propriedades mecânicas do concreto. Para este trabalho foram confeccionados corpos-de-prova cilíndricos e prismáticos nos quais foram adicionados 2% e 5% em volume das fibras à massa do concreto. Após a cura, conforme NBR 5738 (2003) [1], os mesmos foram testados via ensaios de resistência à compressão conforme NBR 5739 (2007) [2], resistência à tração por compressão diametral, conforme NBR 7222 (2011) [3], resistência à tração na flexão conforme NBR 12142 (2010) [4] e módulo de elasticidade estático, conforme NBR 8522 (2008) [5]. Verificou-se após os testes que todos os concretos produzidos atenderam a resistência mínima a compressão de 20 MPa, recomendado pela NBR 6118 (2003) [6] para fins estruturais. Foi observado um aumento da resistência à compressão em relação à mistura padrão. O concreto com adição de fibras de bambu apresentou melhor resistência mecânica em relação ao concreto com adição das fibras de cana-de-açúcar e ao concreto sem adição. Abstract This work aimed to study the influence of the addition of vegetable fibers from bamboo and sugar cane on the mechanical properties of concrete. Implementing the same body-of-proof cylindrical and prismatic, which were added 2% to 5% per volume of fibers to the mass of concrete were made. After healing according to NBR 5738 (2003) [1], they were tested by testing of compressive resistance, according to NBR 5739 (2007) [2], tensile strength by diametric compression according to NBR 7222(2011) [3], tensile strength in bending according to NBR 12142 (2010) [4] and static modulus, according to NBR 8522(2008) [5]. It was found after testing all concretes produced met the minimum strength of 20 MPa recommended by NBR 6118 (2003) [6] for structural purposes. An increased compression resistance compared to the standard mixture was observed. The concrete with added bamboo fibers showed better mechanical strength compared to concrete with the addition of sugar cane sugar and plain concrete fibers.
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