The main deposits of bentonite clays are located in the district of Boa Vista, in the State of Paraiba, Brazil. The random exploration of these deposits for many years is causing the clays to be depleted, and this will turn into a serious problem to the national petroleum industry. So, this work aims to study the characterization of new deposits of bentonite clays in the district of Cubati, in the State of Paraiba, Brazil, with the objective of developing purified organoclays, using a hydrocyclone, from ionic and non-ionic surfactants for use in drilling fluids. The characterization of the studied clay samples was done by applying the following techniques: granulometric analysis by laser diffraction (GA), X-ray diffraction (XRD) and chemical analysis by X-ray fluorescence (EDX) and thermogravimetric (TGA) and differential thermogravimetric (DTA) analysis. The characterization is typical of bentonites and the dispersions present rheological properties which meet Petrobras’ specifications for diesel oil media, organofilized with Praepagen WB.
Organoclays are used as disperse agent in the composition of drilling fluids, which play important roles during the drilling of petroleum wells. This work is intended to develop several kinds of smectite from Cubati-PB for use in drilling fluids, using the ionic surfactant Praepagen WB. The following materials were used: natural Gray and Superior Green bentonite, from the town of Cubati-PB, and quaternary ammonium salts: Praepagen WB® with 45% active matter. The organoclays were characterized by laser diffraction granulometric analysis, chemical composition by X-ray fluorescence, thermogravimetric analysis, differential thermal analysis and X-ray diffraction. In general, we noticed that the clays present diffractograms and thermal behavior typical of bentonites. The results showed that the studied clay has potential for organofilization. With respect to the process variables, we observed that they do not interfere in the organofilization process.
This work aims at the development of organoclay from two varieties of bentonite for use in organic media using ionic surfactants, studying the influence of process variables in the organophilization process. We used the following materials: natural bentonite clay from Cubati-PB District, and the ionic quaternary ammonium salt: Praepagen WB® with 45% active matter. The clays were benefited and then turned into sodium form and subsequently into organoclays. The bentonites were characterized by laser diffraction (GA) X-ray fluorescence chemical composition (EDX), thermogravimetric analysis (TGA), thermogravimetry (DTA) and X-ray diffraction (XRD). The organoclays were characterized by (XRD) thermogravimetric analysis (TGA) and thermogravimetry (DTA). The results showed that the clay has potential for application in the organophilization process and that there is influence of process variables.
The membrane separation processes present several advantages in relation to the traditional process, such as high selectivity, easy operation, good results in the effluent treatments, low energy consumption, small number of processing step, can be applied to thermo sensible substances, easy to combine with other process and scale up, great efficiency in the final product (PORTER, 1990; CAMPOS, 2000). The materials employed in the membrane preparation can be metals, ceramic, polymer or composites.
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