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Presented in several types of food, bioactive amines are described as organic bases of low molecular weight. They have vasoactive, psychoactive and toxicological characteristics and constitute a potential health risk. The concentration of amines formed in foods depends on the type of microorganisms present, the action of decarboxylase enzymes produced by microorganisms on specific amino acids and favorable conditions for enzymatic activity. The presence of these chemical metabolites has been suggested as a quality indicator in routine analyzes for food production and marketing monitoring. The detection of bioactive amines can be performed by chromatographic methods, fluorometric and enzymatic kits. Bioactive amine formation can be prevented mainly through the adoption of good manufacturing practices, but the industry can also use other methods such as temperature control in the production chain, modified atmosphere packaging and food irradiation. This review aims to address the formation of bioactive amines in foods, emphasizing the formation and classification of these metabolites, aspects related to health, acceptable limits, detection methods and control methods used in the industry to ensure food safety and quality. The success of this approach is linked to the importance of bioactive amines as quality indicators, as well as the discussion on the development of methodologies for determining these substances and discussion of acceptable parameters in food.

The effects of polyphosphate on parameters of quality in shrimp (after thawing and cooking) were investigated using physicochemical analytical methods and low-field nuclear magnetic resonance (LF 1 H NMR) spectroscopy. The NMR data were treated by bi-exponential fitting and compared with the physicochemical data. The physicochemical parameters demonstrated that treatments with different concentrations of sodium tripolyphosphate and different time exposures influenced parameters such as cook loss, moisture, pH, color and texture. These differences were reflected in the transverse relaxation (T2) data. Bi-exponential fitting of the T2 resulted in the observation of two water populations in all samples, T21 and T22, with relaxation times in the ranges of 24-47 and 63-120 ms, respectively. Pronounced changes in the T21 and T22 relaxation data were observed during the different treatments, with polyphosphate revealing changes in water properties. Good linear correlations were observed between the T2 parameters and physicochemical data. PRACTICAL APPLICATIONSShrimp processing contains various steps, such as freezing and cooking, which can lead to the denaturation or aggregation of proteins. In this context, the use of polyphosphates prior to the freezing of shrimp can improve yields, water-holding capacity and the sensory attributes of the final product. The fish industry seeks to use polyphosphates in order to optimize production and obtain better quality products. Therefore, studies to identify the ideal phosphate concentration and contact time required for quality production in the frozen shrimp industry are important. Traditional analytical methods for physicochemical measurements are, however, time-consuming, sample destructive and expensive. Low-field 1 H nuclear magnetic resonance is a rapid, noninvasive method to investigate water mobility within materials and foods. The method showed strong correlations with various physicochemical properties, which are important quality factors during shrimp processing. Moreover, the techniques are fast, reliable and nonsample destructive.

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