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We present alkenone‐derived Sea Surface Temperature (SST) records from three marine cores collected within the southern Benguela Upwelling System (BUS) spanning the last 3 ka. The SST evolution over the last 3 millennia is marked by aperiodic millennial‐scale oscillations that broadly correspond to climatic anomalies identified over the North Atlantic region. The BUS SST data further suggest cooling and warming trends opposite to the temperature evolution in the Moroccan upwelling region and in Antarctica. In contrast, the last decades are marked by a cooling of unprecedented magnitude in both the Benguela and Moroccan upwelling systems, which is not observed in the Antarctic record. These contrasted responses in Atlantic upwelling systems triggered by natural and anthropogenic forcings shed light on how different climatic mechanisms are mediated by ocean‐atmosphere interactions and transmitted to the geological records of past and present climate changes.

Soil erosion poses a major threat to sustainable agriculture in southern Africa but is difficult to quantify. One measure of soil erosion is the sediment flux of rivers. The Orange River is the principal source of sediment to the western margin of South Africa with an estimated mean mud flux over the last 11 500 years (the Holocene epoch) of 5.1 (3.2—7.4) million metric tons/year (Mt/yr). A total of 43 gigatons (Gt; 1015 g) representing 72% of the Holocene mud flux has accumulated on the shelf in the Orange River prodelta and mudbelt, a clayey fine-silt deposit focused on the inner to middle shelf. Only 8% (5 Gt) of the mud flux occurs in Holocene calcareous ooze on the slope. Comparison of the clay to mud ratio of offshore deposits with Orange River suspended sediment and catchment soils indicates that 20% (11 Gt) of the Holocene mud flux has been lost as clay beyond the margin. The Orange River mud flux prior to the building of large dams (1930—1969) is ten times greater than the mean Holocene mud flux and is reconciled with estimates of soil erosion within the catchment. A tenfold increase in the Orange River mud flux implies up to a hundredfold increase in total soil erosion depending on the extent of mud storage over periods of decades to centuries within the catchment. Erosion has shifted from areas of high relief and rainfall of the Drakensberg escarpment during the Holocene to intensely cultivated lands of low relief having moderate to high rainfall in the eastern catchment and to a lesser extent, grazing areas of the southern Orange River catchment.

The upper Dwyka and lower Ecca Groups in the Karoo Basin of South Africa document the climatic and palaeoenvironmental changes associated with the final Permo-Carboniferous deglaciation of the Gondwana supercontinent. The depositional environments of these groups have, until recently, been interpreted on the basis of sedimentological and palaeontological evidence. Here we use the geochemistry of early diagenetic concretions -septarian calcite concretions from the upper Dwyka Group and phosphatic chert concretions and beds from the lower Ecca Group -to infer the depositional environment of these rocks in the southwestern Karoo Basin. δ 18 O values (7.8 to 8.9‰ SMOW) suggest that the calcite concretions precipitated from a mixture of meteoric and glacial melt waters rather than Permian seawater. δ 13 C values (−15 to − 3‰ PDB) indicate that the carbon was derived from a mixture of craton-derived calcareous material and organic matter, bacterially degraded in the lower sulphatereduction to upper methanogenesis zones during early burial diagenesis. The rare-earth element (REE) patterns, Sr concentrations and 87 Sr/ 86 Sr ratios (0.716-0.737) significantly greater than Permian seawater (0.708), together also support the interpretation that calcite and phosphatic concretions formed in glacial, fresh water sediments.

The biological pump plays a major role in the transfer of CO2 from the atmosphere to the deep Southern Ocean, a transfer which is largely controlled by the supply of iron and which may partially explain glacial to interglacial variations in pCO2. Analogous to the well‐documented, smaller‐scale “island mass effect,” we propose that the lateral advection of iron by south flowing intermediate waters along the southern African margin may sustain high‐productivity blooms of the Subtropical Convergence Zone (SCZ) between 10 and 70°E. We assess the present‐day interglacial (Holocene) reservoirs and fluxes of organic carbon (OC) and terrigenous mud on the western margin of southern Africa in order to estimate the potential supply of Fe to the Southern Ocean. The highly productive Benguela Upwelling System (BUS) appears to be a relatively inefficient coastal biological pump. Repeated sediment resuspension by wave and tidal energy dissipation limits OC burial to <0.2% of net primary production (NPP) in the southern BUS and to between 0.2 to 2.4% in the northern BUS. Productivity and OC‐rich mud accumulation are focused on the inner portion of the 100–200 km wide shelf which, combined with south flowing bottom currents, limits the export of OC beyond the shelf break to 1.2–8.4% of NPP. However, winnowing of 1 million tons yr−1 of clay particles and the potential early diagenetic benthic (dissolved) Fe flux may supply 10 times more Fe than is transported by dust to the open ocean biological pump of the SCZ. Lowering sea level during glacial periods disperses interglacial mud deposits off the shelf and increases particulate Fe export by as much as a factor of 4. Glacial pulses of margin export may enhance the efficiency of the subantarctic Southern Ocean biological pump and contribute to the initial as well as glacial maximum drawdown in pCO2.