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A series of fluorinated analogues of AOT, the sodium salt of bis(3,

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Carbon aerogels (CAs) were studied as adsorbents for the desulfurization of liquid hydrocarbon fuels for fuel cell applications. A synthetic mixture of dibenzothiophene (DBT) and n-hexadecane (n-HD) was used as a model for sulfur contaminated diesel fuel. Carbon aerogels with two different average pore sizes (4 and 22 nm) were synthesized, characterized, and tested for adsorption of DBT at ambient temperature and atmospheric pressure. The approach-to-equilibrium was monitored, and adsorption isotherms were measured. The CA with the larger average pore size had a higher sulfur adsorption rate and a higher capacity for DBT. The isotherms were best represented by the Freundlich model. According to the Langmuir isotherm, the adsorption capacities of the 4 nm CA and 22 nm CA were 11.2 and 15.1 mg S/g dry CA, respectively. The CAs were found to selectively adsorb DBT over naphthalene, which is a chemically similar but non-sulfur containing organic compound, when both are present in solution. However, the presence of naphthalene slightly reduced the amount of DBT adsorbed.

Aerogels are a special class of nanostructured materials with very high porosity and tunable physicochemical properties. Although a few types of aerogels have already reached the market in construction materials, textiles and aerospace engineering, the full potential of aerogels is still to be assessed for other technology sectors. Based on current efforts to address the material supply chain by a circular economy approach and longevity as well as quality of life with biotechnological methods, environmental and life science applications are two emerging market opportunities where the use of aerogels needs to be further explored and evaluated in a multidisciplinary approach. In this opinion paper, the relevance of the topic is put into context and the corresponding current research efforts on aerogel technology are outlined. Furthermore, key challenges to be solved in order to create materials by design, reproducible process technology and society-centered solutions specifically for the two abovementioned technology sectors are analyzed. Overall, advances in aerogel technology can yield innovative and integrated solutions for environmental and life sciences which in turn can help improve both the welfare of population and to move towards cleaner and smarter supply chain solutions.

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