Neste trabalho é abordada a escolha da pasta de eletrodo para realização da caracterização elétrica de amostras de BaCeO3 dopado com ítrio e contendo ZnO como aditivo de sinterização. A sinterização ocorreu via fase líquida. Foi utilizada uma pasta de eletrodo de platina e outra de prata cujas temperaturas de cura são 1100 °C e 750 °C, respectivamente. A análise das interfaces amostra-eletrodo por microscopia eletrônica de varredura revelou que durante a cura da pasta de platina, devida a elevada temperatura, ocorreu exsudação de fase que permaneceu entre a superfície original da amostra e o eletrodo. Por conseqüência, durante a caracterização elétrica por espectroscopia de impedância foi detectada polarização adicional na interface amostra-eletrodo comprometendo a veracidade dos valores de resistividade elétrica do material em análise o que não ocorreu com o uso do eletrodo de prata devida sua menor temperatura de cura.
Aiming to reducing the gas emissions in the steel mill, in the present study the kinetic behavior of self-reducing pellets containing elephant grass coal and iron ore was investigated through kinetic isotherms for different temperatures. The pellets were isothermally treated in different time intervals for X-Ray diffraction and SEM analyzes. The results obtained by XRD showed that the higher mass of iron in the sample was achieved until the first 24 min. The SEM analysis allowed visualizing the presence of a metallic porous structure closer to edge and whiskers in the center of sample.
The increasing demand for new technologies in the ironmaking/steelmaking field has been motivating several studies towards pelletizing process improvement. Within this context, evaluate the reduction of iron ore pellets using the dilatometer technique constitutes a promising approach for optimizing this process. This paper aims the metallurgical characterization through the sintering of particles in iron ore pellets. With this purpose, some experimental procedures are of concern as follows. Firstly, the kinetic densification of the iron ore pellets is measured using a dilatometer, which heats the samples up at 30 K/min until high temperatures about 1473 K and an isotherm at 10 minutes have been done. Then, the sample is cooled back to room temperature and undergoes a microstructural characterization, with the aid of a scanning electron microscope. At last, the density of the pellets is evaluated, using an Arquimedes Principle and consequently the porosity of the agglomerates. The results indicate the sintering progress of the particles that comprise the pellets as well as reduction the porosity. This behavior is due to the fact that the heat arising from gas induces the partial liquid phase formation and involves the agglomerate particles aiding in the sintering process.
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