This study concerns about the heat transfer behaviour of composite phase change materials (CPCMs) based thermal energy storage components. Two types of components, a single tube and a concentric tube component, are designed and investigated. The CPCMs consist of a molten salt based phase change material, a thermal conductivity enhancement material (TCEM) and a ceramic skeleton material. A mathematical model was established to model the heat transfer behaviour. The modelling results were first compared with experiments and reasonably good agreement with the experimental data was obtained, demonstrating the reliability of the model. Extensive modelling studies were then carried out under different conditions. The influence of thermoproperties, surface roughness and size of the CPCMs as well as heat transfer fluid (HTF) velocity were examined. The results show that the thermal contact resistance between the CPCMs should be considered. Increasing the mass fraction of TCEMs and thickness of CPCMs as well as the HTF velocity intensifies the heat transfer behaviour of component. The concentric tube based component offers a better heat transfer performance compared with the single tube based component, with the total heat storage and release time ∼10 and 15% shorter, respectively, for a given set of conditions.
An electrical thermal storage (ETS) device for space heating is designed in this study. The proposed device is charged by the off-peak electricity and releases its thermal energy to warm the space all day long. The natural convection occurring in the flow channel drives the flowing of air to be heated up and warm the space. The dynamic process of a fully charging/discharging cycle of the device is tested. Meanwhile, a three-dimensional model is developed to simulate the transient thermal behavior. It is found that the experimental and numerical results agree with each other which indicates the validation of the proposed numerical model. The results show that the temperatures of the bricks and the outlet air can be as high as 1002 K and 835 K, respectively. The natural convection occurring in the flow channel transfers 40.4% of the total electrical heating energy to the space for the charging process and 26.9% for the discharging process. Heat losses to the space through the adiabatic material shares 13.3% of the total heating energy for the charging process and 7.2% for the discharging process. Based on those findings, three methods are recommended to improve the device in the successive research.
Thermal energy storage (TES) is a highly effective approach for mitigating the intermittency and fluctuation of renewable energy sources and reducing industrial waste heat. We report here recent research on the use of composite phase change materials (PCM) for applications over 700 °C. For such a category of material, chemical incompatibility and low thermal conductivity are often among the main challenges. Our aims are to address these challenges through the formulation of form-stable composite PCMs and to understand their thermophysical properties. The eutectic K2CO3-Na2CO3 salt was used as a PCM with MgO as a form stabilizer. We found that such a formulation could maintain shape stability with up to 60 wt.% PCM. With a melting point of ~710.1 °C and an energy density as high as 431.2 J/g over a temperature range between 550 °C and 750 °C, the composite PCM was shown to be thermally stable up to 885 °C. An addition of 10 wt.% SiC enhanced the overall thermal conductivity from 1.94 W·m−1 K−1 to 2.28 W·m−1 K−1, giving an enhancement of 17.53%. Analyses of thermal cycling data also showed a high extent of chemical compatibility among the ingredients of the composite PCM.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.