a b s t r a c tCombustion in an O 2 /CO 2 mixture (oxyfuel) has been recognized as a promising technology for CO 2 cap ture as it produces a high CO 2 concentration flue gas. Furthermore, biofuels in general contribute to CO 2 reduction in comparison with fossil fuels as they are considered CO 2 neutral. Ash formation and deposi tion (surface fouling) behavior of coal/biomass blends under O 2 /CO 2 combustion conditions is still not extensively studied. Aim of this work is the comparative study of ash formation and deposition of selected coal/biomass blends under oxyfuel and air conditions in a lab scale pulverized coal combustor (drop tube). The fuels used were Russian and South African coals and their blends with Shea meal (cocoa). A horizontal deposition probe, equipped with thermocouples and heat transfer sensors for on line data acquisition, was placed at a fixed distance from the burner in order to simulate the ash deposition on heat transfer surfaces (e.g. water or steam tubes). Furthermore, a cascade impactor (staged filter) was used to obtain size distributed ash samples including the submicron range at the reactor exit. The deposition ratio and propensity measured for the various experimental conditions were higher in all oxyfuel cases. The SEM/EDS and ICP analyses of the deposit and cascade impactor ash samples indicate K interactions with the alumina silicates and to a smaller extend with Cl, which was all released in the gas phase, in both the oxyfuel and air combustion samples. Sulfur was depleted in both the air or oxyfuel ash deposits. S and K enrichment was detected in the fine ash stages, slightly increased under air combustion conditions. Chemical equilibrium calculations were carried out to facilitate the interpretation of the measured data; the results indicate that temperature dependence and fuels/blends ash composition are the major factors affecting gaseous compounds and ash composition rather than the combustion environment, which seems to affect the fine ash (submicron) ash composition, and the ash deposition mechanisms.

The objective of the present work was to research the storage behavior of a fluidized bed filled with a granular phase change material (PCM) with a small particle diameter (d p = 0.54 mm). The performance of the fluidized bed was compared to that of well-known storage methods such as fluidized beds with sand and packed beds based of sand and PCM. For this purpose, heating experiments were conducted in a cylindrical bed with air as the working fluid.The influence of the bed height and flow rate on the storage and recovery efficiencies of the fluidized bed of PCM was analyzed. Additionally, the stability of the PCM during various charging-discharging cycles was studied.The results indicate that this PCM is an alternative material that can be used in fluidized bed systems to increase the efficiency of storing thermal * Corresponding author. NOTICE: this is the author's version of a work that was accepted for publication in Chemical Engineering Journal. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. The cycling test shows that the PCM is stable under bubbling conditions up to 15 cycles, which corresponds to approximately 75 hours of continuous operation. A definitive version was subsequently published in Chemical Engineering

a b s t r a c tThis paper presents a comparative study on ash deposition of two selected coals, Russian coal and lignite, under oxyfuel (O 2 /CO 2 ) and air combustion conditions. The comparison is based on experimental results and subsequent evaluation of the data and observed trends. Deposited as well as remaining filter ash (fine ash) samples were subjected to XRD and ICP analyses in order to study the chemical composition and mineral transformations undergone in the ash under the combustion conditions. The experimental results show higher deposition propensities under oxyfuel conditions; the possible reasons for this are investigated by analyzing the parameters affecting the ash deposition phenomena. Particle size seems to be larger for the Russian coal oxy fired ash, leading to increased impaction on the deposition surfaces. The chemical and mineralogical compositions do not seem to differ significantly between air and oxyfuel conditions.The differences in the physical properties of the flue gas between air combustion and oxyfuel combus tion, e.g. density, viscosity, molar heat capacity, lead to changes in the flow field (velocities, particle tra jectory and temperature) that together with the ash particle size shift seem to play a role in the observed ash deposition phenomena.

a b s t r a c tThe results from a two fluid Eulerian Eulerian three dimensional (3 D) simulation of a cylindrical bed, filled with Geldart B particles and fluidized with air in the bubbling regime, are compared with experimental data obtained from pressure and optical probe measurements in a real bed of similar dimensions and operative conditions. The main objectives of this comparison are to test the validity of the simulation results and to characterize the bubble behavior and bed dynamics. The fluidized bed is 0.193 m internal diameter and 0.8 m height, and it is filled with silica sand particles, reaching a settle height of 0.22 m. A frequency domain analysis of absolute and differential pressure signals in both the measured and the simulated cases shows that the same principal phenomena are reproduced with similar distributions of peak frequencies in the power spectral density (PSD) and width of the spectrum. The local dynamic behavior is also studied in the present work by means of the PSD of the simulated particle fraction and the PSD of the measured optical signal, which reveals as well good agreement between both the spectra. This work also presents, for the first time, comparative results of the measured and the simulated bubble size and velocity in a fully 3 D bed configuration. The values of bubble pierced length and velocity retrieved from the experimental optical signals and from the simulated particle fraction compare fairly well in different radial and axial positions. Very similar values are obtained when these bubble parameters are deduced from either simulated pressure signals or simulated particle volume fraction. In addition, applying the maximum entropy method technique, bubble size probability density functions are also calculated. All these results indicate that the two fluid model is able to reproduce the essential dynamics and interaction between bubbles and dense phase in the 3 D bed studied.

A new model is proposed for obtaining the velocity profile of the particle ejected from the bubble dome in a freely bubbling 2-D fluidized bed. Its basis is the supposition that the initial velocity of the ejected particles, with a direction perpendicular to the dome contour, depends on bubble velocity and bubble growth velocity. This model differs from those previously appearing in the literature in that it is valid not only for vertical-ascent circular bubbles.Experiments were carried out in a freely bubbling 2-D fluidized bed using a high-speed video camera to measure the velocity profile. Upon comparing these results with the proposed model, it was established that, excepting some isolated cases, the model properly predicts the magnitude and direction of the maximum particle ejection velocity and the velocity profile.Using the work of Shen et al. (2004. Digital image analysis of hydrodynamics two-dimensional bubbling fluidized beds. Chemical Engineering Science 59, 2607-2617), we obtain two general equations for the bubble velocity and the bubble growth velocity in a 2-D fluidized bed. These expressions, together with the proposed model, can be used to calculate the initial velocity of the ejected particles.

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This work presents an experimental study to determine the capacity of a phase change material (PCM) in granular form to be used in fixed and bubbling fluidized beds for thermal energy storage. The experimental measurements are focused on determination of the heat transfer coefficient between a heated surface immersed in the bed and the granular PCM. The flow rate is varied to quantify its influence on the heat transfer coefficient. The PCM used is Rubitherm GR50 with a phase change temperature of approximately 50• C. The PCM is available in two different particle sizes, 0.54 mm and 1.64 mm, of which the finer is used in the fluidized bed and the coarser is used in the fixed bed. In addition, the results obtained for the PCM are compared with the heat transfer coefficients measured for sand, a material commonly used for thermal storage. * Corresponding author. NOTICE: this is the author's version of a work that was accepted for publication in Applied Thermal Engineering. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Applied Thermal Engineering 78 (2015) pp. 373-379. doi:10.1016/j.applthermaleng.2014.12.044 In comparing the heat transfer coefficients for fixed and fluidized beds, the heat transfer coefficients in the fluidized bed with PCM are nearly three times higher than those for the fixed bed at the same gas flow rate. This increase in the heat transfer is a result of two main factors: first, the continuous renewal of PCM particles from the heated surface when they are fluidized, and second, the large quantities of energy in latent form absorbed by the PCM. In the fixed bed there is no renovation of particles, consequently only a small percentage of particles are able to change its phase. Hence, there is no increase in the heat transfer coefficient due to this fact.

This work presents a new methodology, based on the maximum entropy method, to obtain bubble characteristics in fluidized beds. The probability distributions (PDF) of bubble pierced length and velocity are obtained applying the maximum entropy principle to experimental measurements. In addition, the bubble diameter distribution has been inferred from experimental pierced length measurements. This method is applied to characterize bubbles in fluidized beds for the first time and the most general bubble geometry, a truncated spheroid, is considered. The distance between probes, s, which is the minimum pierced length that is possible to measure accurately using intrusive probes, has been introduced as a constraint in the derivation of the size distribution equation. The maximum entropy method is applied to experimental measurements of bubble characteristics carried out using optical and pressure probes in a three-dimensional fluidized bed of Geldart B particles. Results on bubble size obtained from pressure and optical probes are very similar, although optical probes provide more local information and can be used at any position in the bed. The maximum entropy principle has been found to be a simple method that offers many advantages over other methods applied before for size distribution modeling in fluidized beds.