Hafnium dioxide (HfO 2) presents a high crystalline density which makes it attractive for host lattice activated by rare earths for applications as scintillating materials. HfO 2 powders doped with Eu (3+) or Ce (3+) luminescent ions are prepared by sol gel process. The annealing temperature and the concentration of doping ions are optimized to provide the powder presenting the best scintillation yield. The powders are crystallized in monoclinic phase whatever annealing temperature above 800 degrees C. The emission spectra are characterized by a white broadband between 400 and 600 nm. After optimization, the most efficient composition, namely HfO 2:2.5% Eu 1% Y (molar percent) exhibits a scintillation yield about 31,000 photons/MeV, which is about 3.8 times that of the standard Bi 3Ge 5O 12 (BGO) commercial powder.

No abstract

Light manipulation through spin-orbit coupling opens new perspectives in photonics and particularly in integrated optics. The reverse spin Hall effect, where the guided wave direction affects the polarization properties of the light scattered by a nanostructure, is a key effect for the development of new functionalities at the connection between integrated structures and free space, and could find application in chiral quantum optics, modulation, and multiplexing. We show that metasurfaces represent a promising platform for the reverse spin Hall effect. Using a periodic array of-shaped metallic nanoantenna, we control the polarization of the extracted light with the guided wave-propagation direction, but also the number of output directions and the polarization of each one. These results and the versatility of metasurfaces for the spin Hall effect could be extended to various frequencies and materials, such as silicon photonics at telecom wavelength.