The use of state factors can adequately describe the biogeochemistry and geochemistry of relatively undisturbed surface waters. Watersheds with increasing proportions of urban and suburban land use, particularly in sub-tropical, semi-arid and arid urban areas, that utilize irrigation for turfgrass and landscaping may have a low flow urban signature that relates to the source water used by municipal water suppliers. We examined thirteen watersheds; four with waste water treatment plants (24-67% urbanization), four rural (< 30% urbanization) and five urban (> 30% urbanization) in a humid sub-tropical oak savannah in south-central Texas. Three of our urban and one of our rural watersheds displayed the signature of municipal tap water. Three out of four watersheds with waste water treatment plants displayed the signature of treated sewage effluent. We suggest as a result of this study that the chemistry of municipal tap water particularly that with high sodium and bicarbonate, used in urban watersheds for irrigating turfgrass and landscapes may have detrimental effects on base flow stream water quality after it has interacted with watershed soils.

Diffuse sources of surface water pathogens and nutrients can be difficult to isolate in larger river basins. This study used a geographical or nested approach to isolate diffuse sources of Escherichia coli and other water quality constituents in a 145.7-km(2) river basin in south central Texas, USA. Average numbers of E. coli ranged from 49 to 64,000 colony forming units (CFU) per 100 mL depending upon season and stream flow over the 1-year sampling period. Nitrate-N concentrations ranged from 48 to 14,041 μg L(-1) and orthophosphate-P from 27 to 2,721 μg L(-1). High concentrations of nitrate-N, dissolved organic nitrogen, and orthophosphate-P were observed downstream of waste water treatment plants but E. coli values were higher in a watershed draining an older part of the city. Total urban land use explained between 56 and 72 % of the variance in mean annual E. coli values (p < 0.05) in nine hydrologically disconnected creeks. Of the types of urban land use, commercial land use explained most of the variance in E. coli values in the fall and winter. Surface water sodium, alkalinity, and potassium concentrations in surface water were best described by the proportion of commercial land use in the watershed. Based on our nested approach in examining surface water, city officials are able to direct funding to specific areas of the basin in order to mitigate high surface water E. coli numbers and nutrient concentrations.