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employed basalt tephra as an anticorrosive coating on metals, due to its suitable vitrification temperature range. T his preliminary study reveals that basaltic tephra Thus, it was decided to undertake a detailed study of (pumice) is a material suitable for the production of basaltic tephra (available in large quantities in southern high quality ceramics and also provides important Anatolia), mixed with conventional Anatolian clays, as a evidence concerning the transfer of the process of material suitable for the production of high durability manufacture from the laboratory to commercial proceramics, and as an alternative to the more commonly duction. Specifically, the shapes of pores and the uniemployed quartz sands and massive basalt. formity of the pore size frequency distributions in the The aim of this project was to determine the suitability basaltic ceramic preparations are the major textural of basaltic tephra for the production of heavy duty wall properties controlling compressive strength, whereas

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Four novel benzo[c][1,2,5]thiadiazole comprising monomers namely 5-fluoro-6-((2-octyldodecyl)oxy)-4,7-di(thiophen-2-yl)benzo[c][1,2,5]thiadiazole (TBTT), 5-fluoro-4,7-bis(4-hexylthiophen-2-yl)-6-((2-octyldodecyl)oxy)benzo[c][1,2,5]thiadiazole (HTBTHT), 5-fluoro-4,7-di(furan-2-yl)-6-((2-octyldodecyl)oxy)benzo- [c][1,2,5]thiadiazole (FBTF), and 5-fluoro-6-((2-octyldodecyl)oxy)-4,7-bis(thieno[3,2-b]thiophen-2-yl)benzo[c][1,2,5]thiadiazole (TTBTTT) were designed, and synthesized successfully via Stille polycondensation reaction. The structural characterizations of the monomers were performed by 1H and 13C NMR spectroscopy and High Resolution Mass Spectroscopy (HRMS). The monomers were then electropolymerized in a three electrode cell system via cyclic voltammetry. The electrochemical, and spectroelectrochemical characterization of the polymers were reported in detail. Besides, theoretical calculations were performed to elucidate observed experimental properties. According to the cyclic voltammogram of the polymers, HOMO and LUMO energy levels were calculated as −5.68 eV/−3.91 eV, −5.71 eV/−3.72 eV, −5.61 eV/−4.04 eV, and −5.51 eV/−3.71 eV and the electronic band gaps were 1.77 eV, 1.99 eV, 1.57 eV, and 1.80 eV for PTBTT, PHTBTHT, PFBTF, and PTTBTTT, respectively.

The study of İznik ceramics of different periods revealed that temperatures of about 800–900°C were produced during firing. Glass fragments added to the body for strengthening resulted in the formation of fibrous minerals as clusters in the pores and protruding in the glaze together with Ca and P rich minerals in the raw materials used. The pore size distribution of the pores indicates a uniform temperature rise and fall during the production of the microstructure.

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