Segmented block copolymers were synthesized from hydroxyl terminated liquid natural rubber (HTNR) and polyurethane oligomers based on 1,2‐propylene glycol and toluene diisocyanate (TDI) by one‐shot and two‐shot processes in solution. They were completely phase segregated. Structural features were characterized by infrared and nuclear magnetic resonance spectroscopies. The two‐phase morphology was deducted from thermal analysis and dynamic mechanical analysis (DMA). The soft segment glass transition temperature was about −64°C and the hard segment glass transition was between 70°C and 100°C depending on the polyurethane content. The two‐phase morphology was corroborated by a two‐stage thermal decomposition of the products. The morphology consisted of a heterogeneous dispersion of beads in a continuous matrix. The large size and the nature of the beads suggest that they are independent of the block copolymer structure and are formed by the agglomeration of the polyurethane homopolymers, which remain unbonded to the rubber chains during chain extension. At lower hard segment contents the materials behaved like quasi‐elastomers, and at higher hard segment contents, they were like tough plastics. At intermediate compositions they behaved as rigid elastomers. Variations in hardness and tear strength were consistent with this behavior.
Segmented block copolymers were synthesized from hydroxyl-terminated liquid natural rubber and polyurethane oligomers based on Bisphenol A and toluene diisocyanate by one-shot and two-shot processes in solution. Structural features were characterized by infrared and nuclear magnetic resonance spectroscopic analysis. The spectra of the one-shot materials were identical with those of the two-shot materials, indicating their chemical identity. The soft segment T g was well defined and almost invariant around Ϫ64°C, but the hard segment T g varied from 75 to 105°C as the hard segment content increased from 30 to 60 wt %. Two relaxation temperatures were observed for each sample in dynamic mechanical analysis (DMA). These observations and the two-stage thermal decomposition by random nucleation mechanism, as investigated in thermogravimetric analysis unambiguously confirmed complete phase segregation in these materials. The scanning electron microscopy and optical micrographs showed well-defined domains dispersed in a matrix, indicating the two-phase morphology. Systematic changes in hardness and tensile properties with hard segment content were also observed. The samples behaved like soft elastomers at lower hard segment content, toughened plastics at high hard segment content, and rigid elastomers at intermediate compositions. Variations in hardness and tear strength were consistent with this behavior.
Two new cuprous bromide phases Cu 2 (ImH)Br 3 (Im = imidazole) (1) and Cu 3 (Trz) 2 Br 3 (Trz = 1,2,4-triazole) (2) were synthesized by hydrothermal method and characterized by single-crystal X-ray diffraction. The compounds exhibit similar triclinic one-dimensional crystal structures (space group P1) but they are built from two different
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.