[1] The mean composition of mid-ocean ridge basalts (MORB) is determined using a global data set of major elements, trace elements, and isotopes compiled from new and previously published data. A global catalog of 771 ridge segments, including their mean depth, length, and spreading rate enables calculation of average compositions for each segment. Segment averages allow weighting by segment length and spreading rate and reduce the bias introduced by uneven sampling. A bootstrapping statistical technique provides rigorous error estimates. Based on the characteristics of the data, we suggest a revised nomenclature for MORB. "ALL MORB" is the total composition of the crust apart from back-arc basins, N-MORB the most likely basalt composition encountered along the ridge >500 km from hot spots, and D-MORB the depleted end-member. ALL MORB and N-MORB are substantially more enriched than early estimates of normal ridge basalts. The mean composition of back-arc spreading centers requires higher extents of melting and greater concentrations of fluid-mobile elements, reflecting the influence of water on back-arc petrogenesis. The average data permit a re-evaluation of several problems of global geochemistry. The K/U ratio reported here (12,340 AE 840) is in accord with previous estimates, much lower than the estimate of Arevalo et al. (2009) Nd ratio of ALL MORB and N-MORB provide constraints on the hypothesis that Earth has a non-chondritic primitive mantle. Either Earth is chondritic in Sm/Nd and the hypothesis is incorrect or MORB preferentially sample an enriched reservoir, requiring a large depleted reservoir in the deep mantle.

[1] The mean composition of mid-ocean ridge basalts (MORB) is determined using a global data set of major elements, trace elements, and isotopes compiled from new and previously published data. A global catalog of 771 ridge segments, including their mean depth, length, and spreading rate enables calculation of average compositions for each segment. Segment averages allow weighting by segment length and spreading rate and reduce the bias introduced by uneven sampling. A bootstrapping statistical technique provides rigorous error estimates. Based on the characteristics of the data, we suggest a revised nomenclature for MORB. "ALL MORB" is the total composition of the crust apart from back-arc basins, N-MORB the most likely basalt composition encountered along the ridge >500 km from hot spots, and D-MORB the depleted end-member. ALL MORB and N-MORB are substantially more enriched than early estimates of normal ridge basalts. The mean composition of back-arc spreading centers requires higher extents of melting and greater concentrations of fluid-mobile elements, reflecting the influence of water on back-arc petrogenesis. The average data permit a re-evaluation of several problems of global geochemistry. The K/U ratio reported here (12,340 AE 840) is in accord with previous estimates, much lower than the estimate of Arevalo et al. (2009). The low Sm/Nd and 143 Nd/ 144 Nd ratio of ALL MORB and N-MORB provide constraints on the hypothesis that Earth has a non-chondritic primitive mantle. Either Earth is chondritic in Sm/Nd and the hypothesis is incorrect or MORB preferentially sample an enriched reservoir, requiring a large depleted reservoir in the deep mantle.

[1] A large data set of fundamental mode Rayleigh wave amplitudes is analyzed to derive a new global three-dimensional model of shear wave attenuation in the upper mantle. The amplitude observations span a range of periods between 50 and 250 s and are derived from earthquakes with M W > 6.0 that occurred between 1993 and 2005. Four separate factors may influence an amplitude anomaly: intrinsic attenuation along the raypath, elastic focusing effects along the raypath, uncertainties in the strength of excitation, and uncertainties in the response at the station. In an earlier paper (Dalton and Ekström, 2006a), dependence of the retrieved attenuation structure on these terms was shown to be significant and an approach was developed to invert the amplitudes simultaneously for each term. The new three-dimensional attenuation model QRFSI12, which is the subject of this paper, is derived using this method. The model contains large lateral variations in upper-mantle attenuation, ±60% to ±100%, and exhibits strong agreement with surface tectonic features at depths shallower than 200 km. At greater depth, QRFSI12 is dominated by high attenuation in the southeastern Pacific and eastern Africa and low attenuation along many subduction zones in the western Pacific. Resolution tests confirm that the change in pattern of attenuation above and below 200-km depth can be determined with confidence using the fundamental mode data set. The new model is highly correlated with global models of shear wave velocity, particularly in the uppermost mantle, suggesting that the same factors may control both seismic attenuation and velocity in this depth range. However, forcing the lateral perturbations in attenuation to match those found in global velocity models decreases the data variance reduction, which suggests that subtle differences between patterns of attenuation and velocity are robust.