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Anilines react with an array of trialkylamines in the presence of a catalytic amount of RuCl 3 •nH 2 O and bis(diphenylphosphino)methane together with SnCl 2 •2H 2 O and hex-1-ene as hydrogen acceptor in dioxane at 180 °C to afford the corresponding 2,3-disubstituted quinolines in moderate to good yields.

Anilines react with 3‐amino‐1‐propanol in dioxane in the presence of a catalytic amount of a ruthenium catalyst and tin(II) chloride dihydrate together with a hydrogen acceptor to afford the corresponding quinolines in moderate yields.

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