In konzentrierten atherischen Losungen liegen Grignard-Verbindungen uberwiegend in der Form R2Mg + MgXz vor. Die W-chemischen Verschiebungen aliphatischer GrignardVerbindungen sind linear korrelierbar mit denen entsprechender Kohlenwasserstoffe. Allylund Cyclopentadienylmagnesiumbromid zeigen austauschentartete W-Spektren. Fur alkylsubstituierte Benzole konnten die Linien zugeordnet werden.
13C-NMR-Spectroscopic Investigations of Grignard CompoundsGrignard reagents occur predominantly as R2Mg + MgX2 in concentrated diethyl ether
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