In the present work, single layer graphene nanoplatelets (GNPs) derived from waste tires by recycling and upcycling approaches were integrated in homopolymer (Homo-) and copolymer (Copo-) polypropylene (PP) matrices by fast and efficient mixing in the melt phase. The effect of GNP content on crystallization and mechanical behaviors was investigated in detail at different loading levels. Regarding isothermal and non-isothermal crystallization experiments, GNPs significantly accelerated the nucleation and growth of crystallites, and the crystallization degree in Homo-PP nanocomposites was slightly higher than that of Copo-PP based nanocomposites. Also, there was significant improvement in mechanical and thermal properties of GNP reinforced polymers compared to neat polymers. As the GNP concentration increased from 1 to 5 wt%, there was a gradual increase in flexural modulus and strength values. In tensile tests, an increase in GNP content in both polymer grades led to a slight increase in yield strength coming from the proper distribution of nano-reinforcement by creating stress concentration sites. After the yield point, Homo-PP based nanocomposites showed higher strain hardening than GNP reinforced Copo-PP owing to a high crystallization degree and linear chains of Homo-PP. This work showed that functionalized graphene can act as both nucleating and reinforcing agent in the compounding process and its exfoliation through polymer chains is much better in homopolymers at a faster and high shear rate.
Lightweighting is a challenge for the automotive industry, and foaming is a key technology used to address this problem. A new practical approach is studied to regulate the cell formation of copolymer polypropylene (co-PP) by utilizing graphene nanoplatelets (xGnP) as a process aid during foam injection molding. The approach was designed to enable process freedom to tune part performance by adjusting the amount of xGnP masterbatch. Two different levels of 1–2 wt % xGnP and 0.25–0.35 wt % supercritical fluid (SCF) were investigated. Prepared samples were compared with samples prepared by the traditional method (twin-screw extrusion followed by foam injection molding). The nanocomposite with 2 wt % xGnP comparatively showed about twofold reduction in cell size magnitude. Although the increment in SCF amount resulted in a 47% and 122% enhancement in flexural modulus and strength, respectively, and a 45% loss in Izod unnotched impact strength, the cell size was prone to increasing with regard to low melt strength as compared to neat foams. In conclusion, a 12% weight reduction fulfilled the desired performance parameters in terms of mechanical and sound insulation by utilizing 2 wt % xGnP as a process aid.
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