Back Cover: In article number 1900160, Burak Akdeniz and Emre Bukusoglu describe a new method that combines lithography with liquid‐crystalline molecular templates for the synthesis of polymeric microparticles. This method provides precise control over the size, aspect ratio, internal structuring, and chiral twisting of the microparticles.
Liquid crystals (LC), when combined with photolithography, enable synthesis of microparticles with 2D and 3D shapes and internal complexities. Films of nematic LCs are prepared using mixtures of reactive (RM257) and non‐reactive mesogens with controlled alignment of LCs at the confining surfaces, photo‐polymerized the RM257 using a photomask, and then extracted the unreacted mesogens to yield the polymeric microparticles. The extraction results in a controlled anisotropic shrinkage amount dependent on the RM257 content and the direction dependent on LC alignment. Control over the aspect ratio, size, and thickness of the microparticles are obtained with a coefficient of variance less than 2%. In addition, non‐parallel LC anchoring at the two surfaces results in a controllable right‐ or left‐handed twisting of microparticles. These methods may find substantial use in applications including drug delivery, emulsions, separations, and sensors, besides their potential in revealing new fundamental concepts in self‐assembly and colloidal interactions.
The
design parameters and principles for the synthesis of polymeric
microscopic objects using a method that combines photolithography
and liquid crystal (LC) molecular templates have been demonstrated.
Specifically, mixtures of a reactive mesogen (RM257) and nonreactive
LC (E7) were polymerized using
UV light and a photomask. We used photomasks with circular, triangular,
rectangular, square, star-shaped, and heart-shaped features to provide
initial shapes to the objects. Then, the unreacted parts were extracted
and the polymeric objects were allowed to shrink anisotropically as
defined by the ordering symmetry of the LC mixture. The initial configuration
of the LC mixtures played a critical role in determining the final
shapes of the polymeric objects formed after shrinking, which resulted
in chiral twisting and bending, leading to more than 20 different
shapes. We found that the pitch size of the bulk chiral twisted objects
depends linearly on the angle of chiral twist of the LCs, whereas
it was independent of their thickness and length ranging from 1.5
to 160 μm and 100 μm to 2.45 cm, respectively. The shapes
of the polymeric objects synthesized from LC films with bent LC ordering,
however, were critically dependent on the thickness of the objects
due to the interplay between the elastic energy and surface anchoring
of the LCs. The critical role of LC elasticity was observed for thicknesses
below 20 μm, above which surface anchoring was dominant in determining
the shapes. Overall, the proposed method was shown to provide a precise
control over the three-dimensional architectures of the objects with
size range that covers the micro and macro scales, which would find
use in fields ranging from emulsion stabilization and catalysis to
micromachines and artificial muscles.
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