Mining environmental liabilities (MEL) are of great concern because of potential risks to ecosystems and human health. In this research, the environmental risk (RI) related to MEL existing in three artisanal and small-scale gold-mining areas of Ecuador was evaluated. For this purpose, data of 167 MEL including landfills, mining galleries, tailing deposits, and mineral processing plants from Macuchi, Tenguel–Ponce Enriquez, and Puyango mining areas, were analyzed. The risk assessment related to the presence of waste deposits was carried out based on the methodology proposed by the Spanish Geological Survey. Moreover, the procedure outlined in the Environmental Risk Assessment Guide of the Ministry of Environment of Peru for nonwaste deposits was applied. The highest RI values were identified in Puyango and Tenguel–Ponce Enriquez. Thus, they were both categorized as priority control areas requiring intervention and rehabilitation plans. The MEL that require a high level of intervention include waste deposits and mine entrances associated with potentially toxic elements. Moreover, the point risk maps showed that rivers in the studied areas have a potential pollution risk. This study provides risk levels associated with MEL in mining areas from Ecuador. This information could be used for environmental management and pollution mitigation.

Consumption of food grown in contaminated soils may be a significant human exposure pathway to pollutants, including toxic elements. This study aimed to investigate the pollution level of trace elements in farmland soil and crops collected in orchards from Ponce Enriquez, one of the Ecuador’s most important gold mining areas. The concentration of arsenic (As), cadmium (Cd), chrome (Cr), copper (Cu), nickel (Ni), lead (Pb), and zinc (Zn) was analyzed in soil and crop samples (celery, chives, corn, herbs, lettuce, turnips, green beans, cassava, and carrots). In addition, a probabilistic human health risk assessment, in terms of hazard quotients (HQ) and cancer risk (CR), was conducted to assess the potential risk related to local crop ingestion. The contents of As, Cr, Cu, and Ni in soils exceeded the Ecuadorian quality guidelines for agricultural soils. The trace elements concentration in local crops was higher than the maximum permissible levels set by the Food and Agriculture Organization of the United Nations (FAO). The HQ and CR of local crop ingestion were several orders higher than the safe exposure threshold, mainly for lettuce, chives, and turnips. Our results revealed that inhabitants of the study area are exposed to developing carcinogenic and non-carcinogenic effects due to long-term food consumption with high trace elements. This study sheds light on the need to assess further the quality of agricultural soils and crops grown in mining areas with signs of contamination to guarantee consumer food safety.

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