Two simple chemosensors
with urea (L1) and thiourea (L2) groups
were synthesized and studied by different spectroscopic techniques.
Both receptors can sense acetate (Ac
–
), dihydrogen
phosphate (H
2
PO
4
–
), and fluoride
(F
–
) anions, accompanied by changes in UV–vis
and
1
H NMR spectra, and an optical response is observed
as a color change of the solutions due to deprotonation and hydrogen-bonding
processes. Also, L1 and L2 were supported on TentaGel resins (R1 and
R2), and their fluoride-sensing properties in DMSO and water solutions
were studied. Interestingly, R2 can sense fluoride ions in sample
solutions of 100% water.
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