Recently, a new fiber-laden, self-diverting, and viscoelastic acid has been successfully used for matrix acidizing of highly heterogeneous carbonate formations The fibers have been designed to be inert under surface and pumping conditions, and their geometry allows them to form strong and stable fiber networks that can effectively bridge across natural fractures, wormholes, and perforation tunnels. Eventually, the fibers degrade into a water-soluble organic liquid that is produced back to the surface during flowback.In the case of perforated wells, experiments suggest that diversion with fibers operates in three phases. First, as the early volumes of fiber-laden acid reach the perforations, the acid penetrates the reservoir as if no fibers were present. Second, as the fibers bridge, they accumulate inside the perforations and form a fiber cake. Third, the fibers plug the perforation, and the injectivity decreases locally, promoting diversion into other perforations. The pressure drop through a plugged perforation was analyzed by performing 340 separate fine-scale 3D simulations. The original work was based on theoretical and laboratory-based experiments, considering typical perforation schemes and for various permeability ratios between the generated fiber cake and the formation's original permeability. The results were compiled, and a correlation was made to model the resulting skin. The model was implemented into an acid placement simulator and was extensively tested and validated in the field.In this paper, we present the model that describes the effect of fiber accumulation within perforations and explain how some of the model parameters such as formation-permeability contrast, fiber-cake permeability, and total permeability thickness (kh) may affect diversion efficiency. Case studies from field testing of the model illustrate methods of pressure history matching, job design, and treatment history evaluation.
Gas production from the unconventional Barnett Shale reservoir now exceeds 3 Bcf/d, which is more than 5% of total U.S. dry gas production. Typically Barnett Shale wells exhibit a rapid production decline following the initial hydraulic fracture stimulation treatment, so that, within 5 years, an operator is normally faced with a well producing below its economic threshold. To keep up with current gas demand, operators have moved to an aggressive horizontal drilling and completion program. Additionally, in an effort to increase the productivity of existing wells and book additional reserves at reduced cost, operators have restimulated their older vertical wells, with demonstrable success. This success is providing compelling opportunities to enhance refracture treatment coverage by targeting bypassed and ineffectively stimulated zones in additional vertical wells and even some horizontal wells. Because of the heterogeneous nature of this unconventional gas reservoir, the restimulation of horizontal wells is problematic, and operators have demonstrated limited success using current stimulation techniques. This paper describes a new fracture diversion technique particularly adapted for horizontal well refracture stimulation. During the treatment, a fracture diversion system (FDS) is used to create a temporary bridge within the active fracture networks. That results in differential pressure increase and causes treatment redirection to understimulated intervals along the lateral. This technique enables both fracture diversion without mechanical intervention and, when enhanced with microseismic monitoring, real-time optimization of the fracturing treatment. Refracture stimulation case studies are presented in which this novel diversion technique is successfully applied to horizontal Barnett Shale wells. This paper demonstrates how real-time hydraulic fracture monitoring has enabled operators to make informed decisions that influence fracture geometry, increase lateral coverage, and improve gas recovery. To date, more than 20 fracture diversion designs have been successfully placed. The trial wells have included both cemented and uncemented completions, with drilled azimuths selected to encourage either transverse or longitudinal fracture fairway development. With a continuing optimization of the described refracturing technique, these FDS designs and placement strategies have evolved to the point where they are consistently exhibiting fracture diversion as evidenced by movement of microseismic activity and improved lateral coverage. While this engineered fracture diversion technique is ideally suited for re-fracture stimulations, it is also applicable for stimulation of new wells where the technique enables stimulation of larger wellbore intervals when used in the same fashion as for re-fracture stimulation applications. Introduction The Barnett Shale is a Mississippian-age marine shelf deposit that unconformably lies on the Ordovician-age Viola Limestone/Ellenberger group and is conformably overlain by the Pennsylvanian-age Marble Falls Limestone (Ketter et al. 2006). Formation thickness varies from 200 to 800 ft through the reservoir. The productive rock is typically a black, organic-rich shale with ultralow permeability in the range of 70 to 500 nanodarcy. To attain economically viable production rates, hydraulic fracture stimulation is a necessity.
fax 01-972-952-9435. AbstractSelf-diverting acids are commonly used in matrix acidizing treatments of carbonate formations, not only to increase permeability by generating wormholes, as with conventional acids such as HCl, but also to self-divert into zones of lower injectivity, in the goal of optimizing zonal coverage. In this paper, a new model for wormhole propagation is proposed, which describes both stimulation and diversion processes. A preliminary model is presented, which predicts wormhole propagation under radial-flow conditions for conventional acids. Then, a new set of parameters characterizing the reactive flow of self-diverting acids is developed, and the above model is extended to include self-diverting mechanisms. In particular, it is shown how the new parameters related to wormhole growth and those to diversion can be assessed from linear core-flood experiments and integrated into a new radial-flow model for field-scale prediction. Using this model, a new criterion is developed for diverter efficiency as a function of permeability contrast. Finally, the model is validated against radial flow experiments. It is found that self-diverting acids are characterized by two new parameters which, when combined with the model for wormhole propagation, can be used to predict the performance of self-diverting acids, both in terms of wormhole penetration and in terms of zonal coverage. Some criteria are also developed to assess the diversion ability of acids.
Summary Dissolution kinetics of analcime (a zeolite), chlorite, and illite (layered aluminosilicates) are examined in hydrochloric and mixtures of hydrochloric and hydrofluoric acid systems. Dissolution kinetics were determined from batch reactor experiments in the temperature range of 25 to 100°C. The reaction progress was monitored by analysis of Al, Si, Fe, Mg, and Na concentrations in the aqueous phase. The reactivity of these aluminosilicates was compared with that of kaolinite under similar experimental conditions. Models for the reaction of the aluminosilicates with each acid are presented. The reaction kinetics incorporated into a geochemical simulator predict matrix-stimulation results for formations containing these minerals. Guidelines for design of matrix-stimulation treatments for acid-sensitive formations are formulated. Introduction Sandstone acidizing is a complex operation because the treatment involves flow and reactions in porous media where the reactive chemicals can contact a wide range of minerals. The formation may contain various amounts of silica (SiO2), clays (aluminosilicates such as kaolinite or illite), or alkaline aluminosilicates such as feldspar and zeolites, as well as calcium and magnesium carbonates. Recent studies on matrix stimulation have strongly emphasized the importance of secondary and tertiary reactions in determining the success of matrix treatments (Gdanski 1996, 1997a). However, for acid-sensitive aluminosilicates, these reactions are especially important because they occur at much shorter time scales than for the nonacid-sensitive minerals. The presence of acid-sensitive aluminosilicates may dominate treatment design considerations, even though they may be present in small quantities compared to other aluminosilicates. Appropriate selection of treatment fluids is key in preventing formation damage in presence of acid-sensitive aluminosilicates. However, the extent of secondary and tertiary reactions under reservoir conditions for each fluid and mineral is difficult to quantify with laboratory testing alone (Ziauddin et al. 2002a). In this study, a combination of laboratory testing and geochemical simulations have been used to elucidate the underlying reaction mechanisms for these minerals and to determine their impact on reservoir treatments.
fax 01-972-952-9435. AbstractSelf-diverting acids are commonly used in matrix acidizing treatments of carbonate formations, not only to increase permeability by generating wormholes, as with conventional acids such as HCl, but also to self-divert into zones of lower injectivity, in the goal of optimizing zonal coverage. In this paper, a new model for wormhole propagation is proposed, which describes both stimulation and diversion processes. A preliminary model is presented, which predicts wormhole propagation under radial-flow conditions for conventional acids. Then, a new set of parameters characterizing the reactive flow of self-diverting acids is developed, and the above model is extended to include self-diverting mechanisms. In particular, it is shown how the new parameters related to wormhole growth and those to diversion can be assessed from linear core-flood experiments and integrated into a new radial-flow model for field-scale prediction. Using this model, a new criterion is developed for diverter efficiency as a function of permeability contrast. Finally, the model is validated against radial flow experiments. It is found that self-diverting acids are characterized by two new parameters which, when combined with the model for wormhole propagation, can be used to predict the performance of self-diverting acids, both in terms of wormhole penetration and in terms of zonal coverage. Some criteria are also developed to assess the diversion ability of acids.
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