The final addition to the tris(azolyl)borate ligand family, tris(1,2,3-triazolyl)borate, has been synthesized. The sodium salt of the ligand forms a complex polymeric structure where both N2 and N3 bind to crystallographically independent sodium ions. Depending on the divalent transition metal, tris(1,2,3-triazolyl)borate forms either molecular homoleptic complexes or coordination polymers.
A series of isoreticular two-dimensional metal–organic frameworks (MOFs) was synthesized with group 11 metals and semirigid ligands that bind in a syn conformation.
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