Organic photovoltaic cells (OPVs) are promising solar electric energy conversion systems with impressive recent optimization of active layers. OPV optimization must now be accompanied by the development of new charge-selective contacts and interlayers. This Perspective considers the role of interface science in energy harvesting using OPVs, looking back at early photoelectrochemical (photogalvanic) energy conversion platforms, which suffered from a lack of charge carrier selectivity. We then examine recent platforms and the fundamental aspects of selective harvesting of holes and electrons at opposite contacts. For blended heterojunction OPVs, contact/interlayer design is especially critical because charge harvesting competes with recombination at these same contacts. New interlayer materials can modify contacts to both control work function and introduce selectivity and chemical compatibility with nonpolar active layers and add thermodynamic and kinetic selectivity to charge harvesting. We briefly discuss the surface and interface science required for the development of new interlayer materials and take a look ahead at the challenges yet to be faced in their optimization.
Electrochemistry at individual metal nanoparticles (NPs) can provide new insights into their electrocatalytic behavior. Herein, the electrochemical activity of single AuNPs attached to the catalytically inert carbon surface is mapped by using extremely small (≥3 nm radius) polished nanoelectrodes as tips in the scanning electrochemical microscope (SECM). The use of such small probes resulted in the spatial resolution significantly higher than in previously reported electrochemical images. The currents produced by either rapid electron transfer or the electrocatalytic hydrogen evolution reaction at a single 10 or 20 nm NP were measured and quantitatively analyzed. The developed methodology should be useful for studying the effects of nanoparticle size, geometry, and surface attachment on electrocatalytic activity in real-world application environment.
We report the characterization of the frontier orbital energies and interface dipole effects for bare and ligand-capped 3.6 and 6.0 nm diameter CdSe nanocrystals (NC) tethered to smooth gold substrates, using He(I) and He(II) UV photoemission spectroscopy. Changes in the ionization potential (IP) of the NCs and local effective work function of the films were explored as a function of the dipolar nature of the NC capping ligands. The addition of thiol-capping ligands 1-hexanethiol, 1-benzenethiol, and 4-fluorothiophenol to both sizes of NCs produces negligible shifts in energy offset between the high kinetic energy edge of the CdSe NCs and the gold substrate Fermi energy. However, the local vacuum level and IP of the nanocrystal layer are altered by as much as 0.3 eV. We demonstrate the importance of determining both the local vacuum level and the high kinetic energy edge of a tethered NC sample. These studies demonstrate a method that can be used in the future to characterize the frontier orbital energy offsets for modified or unmodified nanocrystalline films, in which the NCs are incorporated into host materials, for applications ranging from photovoltaics to light-emitting diodes.
Kinetic Monte Carlo simulations of planar heterojunction (PHJ) organic solar cells (OPVs) constructed with electronically heterogeneous electrodes are presented which correlate the extent and length scale of electrode heterogeneity with their capacity for collecting photogenerated charge carriers. The PHJ OPV is modeled as an ensemble of discrete 1 nm3 molecular sites and 1 nm2 electrode sites for which we individually assign various effective activation energies for charge hopping. Utilizing Marcus theory to describe charge transfer reactions within the energetically disordered lattice, described by a Gaussian distribution of discrete site energies, we demonstrate the sensitivity of solar cell device performance to nanometer length scale heterogeneity at the electrode-active layer contact. Such sensitivity is reflected in the steady-state charge density profiles in the vicinity of the electrode-active material interface, charge collection efficiencies, and rates of recombination at the donor–acceptor (D/A) interface. Additionally, we demonstrate how implementation of idealized interlayers placed between the electrode and active layer functions to mitigate the negative effects of electrode heterogeneity.
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