[1] Proximity balloon soundings for snow events with lightning and thunder during the period 1961 through 1990 reveal a less statically stable environment than similar nonthundering snow events. When thundersnow is present, a less stable environment (and in some cases subsequent upright convection) is found aloft in all of the thundering cases examined here; all of the events feature their most unstable parcel originating above a frontal inversion. In fact, only events in the cold air north of an extratropical cyclone are included in this study. Events with a lake effect or orographic enhancement are eliminated from the sample. The basic composite derived by averaging temperatures at an established interval reveals a nearly saturated lower atmosphere, below 0°C throughout its depth, with the frontal inversion present and its most unstable parcel occurring just above the top of the inversion. The feature-preserving composite approach of R. A. Brown (1993) better defines the frontal inversion bottom and top as well as the level and temperature of the most unstable parcel; these are the features in need of preservation, and a less statically stable environment emerges by doing so. Other salient features include the most unstable parcel originating some 30-50 mbar above the top of the frontal inversion and significant drying $100 mbar above the level of the most unstable parcel. The bulk sounding characteristics also favor the existence of lightning. The composite temperature at the level of the most unstable parcel is À8.7°C, which allows for enhanced amounts of supercooled water to enter any updraft that may form. The temperature of the most unstable parcel at its origin is also warmer than the charge reversal temperature; therefore convection of any appreciable depth will span that level. Moreover, the height of the composited À10°C level is 2959 m above ground level, which previous investigators have shown is sufficiently high to favor lightning production. Yet no convective available potential energy (CAPE) appears with either composite approach, which concurs with previous studies. While several of the composite members feature CAPE for elevated layers, the majority do not, suggesting that other processes (e.g., the release of symmetric instability), which are difficult to assess from a single sounding, tend to be at work.
Between 2100 UTC 11 February 2003 and 0200 UTC 12 February 2003, a line of thunderstorms passed swiftly through parts of eastern Iowa and into north-central Illinois. Although this storm somewhat resembled a warm season, line-type mesoscale convective system, it was unique in that the thunderstorm winds exceeded the severe criterion (50 kt; 25.7 m s 21 ) during a snowburst. While the parent snowband deposited only 4 cm of snow, it did so in a short period and created a treacherous driving situation because of the ensuing near-whiteout conditions caused by strong winds that reached the National Weather Service severe criteria, as the line moved across central Illinois. Such storms in the cold season rarely occur and are largely undocumented; the present work seeks to fill this void in the existing literature.While this system superficially resembled a more traditional warm season squall line, deeper inspection revealed a precipitation band that failed to conform to that paradigm. Radar analysis failed to resolve any of the necessary warm season signatures, as maximum reflectivities of only 40-45 dBZ reached no higher than 3.7 km above ground level. The result was low-topped convection in a highly sheared environment. Moreover, winds in excess of 50 kt (25.7 m s 21 ) occurred earlier in the day without thunderstorm activity, upstream of the eventual severe thundersnow location. Perhaps of greatest importance is the fact that the winds in excess of the severe criterion were more the result of boundary layer mixing, and largely coincident with the parent convective line. This event was a case of forced convection, dynamically linked to its parent cold front via persistent frontogenesis and the convective instability associated with it; winds sufficient for a severe thunderstorm warning, while influenced by convection, resulted from high momentum mixing downward through a dry-adiabatic layer.
[1] A comparison of 30 years of hourly surface weather observations (1960 -1991) from first-order stations and 24-hour snowfall data from climate network stations over the upper Midwestern United States reveals an indirect association between the relatively rare occurrence of thundersnow (<1 event yr À1 in this dataset) and the accumulation of significant 24-hour snowfall (>15 cm) in 19 of 22 cases identified. Although no direct relationship is found between the location of thundersnow and the deepest 24-hour snow totals, significant snow accumulations frequently occurred in proximity (<1°latitude) to thundersnow events. The presence of thundersnow tended to indicate a parent extratropical cyclone capable of producing significant snowfall totals; should thundersnow be anticipated, the operational meteorologist can have much greater confidence in forecasting deeper snow totals.
A spectrophotometric titration was performed to determine water hardness. The titration incorporated the traditional titration method employing EDTA as the titrant and calmagite as the indicator. The microscale experiment was carried out in a spectrometer cuvette and made use of a Texas Instruments (TI-83) calculator interfaced through a TI Calculator-Based Laboratory system to a Vernier colorimeter as the detector. Monitoring at 635 nm, one of the colorimeter's fixed wavelengths, was well suited for this analysis. Agreement was found with results from traditional titrations.
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