The world has become increasingly aware of environmental issues through discussions about the greenhouse effect, ozone layer depreciation, water pollution and waste disposal. The role of the chemical industry in introducing contaminants into the environment has been much criticised. But how far can this be justified? Brian Glover and Jeff Pierce discuss the issues as seen by one of the world's major colorant manufacturers.
In order to more fully understand the factors that influence the thermal “hot-spot” initiation of high explosives, we have chosen a model system for study that uses the internal and localized dissipation of long wavelength electromagnetic energy (microwaves). High purity organic crystals generally interact weakly with microwave energy. Therefore, the addition of electromagnetically absorbing inclusions of silicon carbide provides a tractable system for the study of hot-spot ignition phenomena. Previously, we developed a simple analytic model that illuminates the important physical factors. In this work, we verify the relationships of the analytic model using a series of experiments and a numerical model.
Microwave frequency electromagnetic properties are critical for understanding and predicting the heating and ignition behavior of explosives subjected to microwave irradiation. In this work we report relative complex permittivity measurements in the X‐band (8–12 GHz) for 13 neat explosives measured by the circular cavity technique. This data set was then used in conjunction with COMSOL 4.3 Multiphysics® finite element analysis software to design and simulate a low power (100 W), high electric field X‐band microwave applicator. The role of the sample holder on our ability to directly study the response of explosives to electromagnetic energy is examined and shown to be critical. Times to ignition were predicted for PETN, TATB, and HMX and indicate that for the proposed applicator and considered properties ignition may occur in less than one second exposure. These predictions show that explosives can be effectively heated in short time scales through direct microwave heating without absorptive binders or inclusions.
A model for electromagnetically induced hot spots is developed from the well-established theories of dielectric mixtures, microwave absorption, heat transfer, and thermal ignition. This mathematical model is used to elucidate the interplay among these theories for a microwave heated system of secondary high explosive within which isolated electromagnetically lossy spheres are randomly distributed. Results are shown in this article for the specific case of pentaerythritol tetranitrate with embedded spheres of varying diameter and conductivity illuminated by a uniform time harmonic electromagnetic field of 1, 8, and 15 GHz. It is shown that for a given frequency and electric field strength internal to a particle embedded in a secondary high explosive, there exists a range of values for the particle’s diameter and conductivity for which electromagnetically induced hot-spot ignition of the high explosive is possible. By providing an accurate estimate for the range of necessary geometric and electrical properties of the system, this idealized model can be used to guide potentially complex and otherwise less tractable computational and experimental studies of microwave-induced hot spots. We found that the condition of relatively large particles, with semiconductorlike conductivity, exposed to the highest possible frequency is most favorable for hot-spot ignition.
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