It is well known that there is no ''universal'' permeability-porosity relationship valid in all porous media. However, the evolution of permeability and porosity in rocks can be constrained provided that the processes changing the pore space are known. In this paper, we review observations of the relationship between permeability and porosity during rock evolution and interpret them in terms of creation/destruction of effectively and non-effectively conducting pore space. We focus on laboratory processes, namely, plastic compaction of aggregates, elastic-brittle deformation of granular rocks, dilatant and thermal microcracking of dense rocks, chemically driven processes, as a way to approach naturally occurring geological processes. In particular, the chemically driven processes and their corresponding evolution permeability-porosity relationships are discussed in relation to sedimentary rocks diagenesis.
Fracture pattern development has been a challenging area of research in the Earth sciences for more than 100 years. Much has been learned about the spatial and temporal complexity inherent to these systems, but severe challenges remain. Future advances will require new approaches. Chemical processes play a larger role in opening‐mode fracture pattern development than has hitherto been appreciated. This review examines relationships between mechanical and geochemical processes that influence the fracture patterns recorded in natural settings. For fractures formed in diagenetic settings (~50 to 200 °C), we review evidence of chemical reactions in fractures and show how a chemical perspective helps solve problems in fracture analysis. We also outline impediments to subsurface pattern measurement and interpretation, assess implications of discoveries in fracture history reconstruction for process‐based models, review models of fracture cementation and chemically assisted fracture growth, and discuss promising paths for future work. To accurately predict the mechanical and fluid flow properties of fracture systems, a processes‐based approach is needed. Progress is possible using observational, experimental, and modeling approaches that view fracture patterns and properties as the result of coupled mechanical and chemical processes. A critical area is reconstructing patterns through time. Such data sets are essential for developing and testing predictive models. Other topics that need work include models of crystal growth and dissolution rates under geological conditions, cement mechanical effects, and subcritical crack propagation. Advances in machine learning and 3‐D imaging present opportunities for a mechanistic understanding of fracture formation and development, enabling prediction of spatial and temporal complexity over geologic timescales. Geophysical research with a chemical perspective is needed to correctly identify and interpret fractures from geophysical measurements during site characterization and monitoring of subsurface engineering activities.
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