The complex refractive index of polydimethylsiloxane (PDMS) is determined in the wavelength range between 2.5 μm and 16.7 μm. The parameters of a Drude-Lorentz oscillator model (with 15 oscillators) are extracted from Fourier transform infrared spectroscopy reflectance measurements made on both bulk PDMS and thin films of PDMS deposited on the gold coated silicon substrates. It is shown that thin films of PDMS atop gold exhibit selective emission in the 8 μm to 13 μm atmospheric transmittance window, which demonstrates that PDMS, especially due to its ease of deposition, may be a viable material for passive radiative cooling applications.
In this work, we present an expression for the near-field thermal radiative transfer between two spheres with arbitrary numbers of coatings. We numerically demonstrate that the spectrum of heat transfer between layered spheres exhibits novel features due to the newly introduced interfaces between coatings and cores. These features include broad super-Planckian peaks at non-resonant frequencies and near-field selective emission between metallic spheres with polar material coatings. Spheres with cores and coatings of two different polar materials are also shown to exceed the total conductance of homogeneous spheres in some cases.
The scalability and implementation of selective emitters in passive radiative cooling applications are limited by the high fabrication costs due to the complexity of these structures. The usage of commercially available polymers in selective emitters holds potential in lowering the cost of radiative cooling solutions. In this work, we demonstrate that thin films of polydimethyl-siloxane (PDMS) on aluminum substrates act as radiative coolers by selectively emitting in the wavelength range of 8 μm to 13 μm, where the Earth’s atmosphere is highly transparent. We also show that our device can achieve passive cooling up to 12 °C below the ambient temperature under the night sky. This suggests that PDMS, especially due to its ease of deposition, may be a viable selective emitter in passive radiative cooling applications.
In this work, we present expressions for radiative heat transfer between pairs of spheres in a linear chain and between individual spheres and their environment. The expressions are valid for coated spheres of arbitrary size, spacing, and isotropic optical properties. The spheres may be small and closely-spaced, which violates the assumptions foundational to classical radiative transfer. We validate our results against existing formulations of radiative heat transfer, namely the thermal discrete dipole and boundary element methods. Our results have important implications for the modeling and interpretation of near-field radiative heat transfer experiments between spherical bodies.
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