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The presence of pharmaceuticals in the environment has increased. These pollutants are toxic and non-biodegradable. Piroxicam (PRX) is a non-steroidal anti-inflammatory drug that ends up in wastewater via pharmaceutical industry activities and human being consumption. This work aimed to study the pharmaceutical pollutant removal from wastewater using agricultural by-products as low-cost adsorbent material. Different parameters were studied, such as time, initial adsorbate concentrations, and temperature. The study of the initial concentration-effect shows that the greatest amount of adsorbed is observed in low concentrations. The temperature has shown a negative effect in this study. The kinetics show that after 45min, the equilibrium is obtained; that means the exhaustion of all active sites. The representative model of this adsorption is the Langmuir isotherm according to the regression coefficient, which is equal to 0.99. The natural abundance of this material and the low cost of investment could offer a good alternative to other more expensive adsorbents such as activated carbon.

Food coloring has become one of the main sources of water pollution. Brilliant blue (BB) is one of the dyes used in the food industry. Heterogeneous photocatalysis is increasingly used to decontaminate polluted water from food industries. The objective of this paper was to treat this pollution using a photoreactor at the laboratory (batch) and pilot scales. The photodegradation of the brilliant blue dye, chosen as a model of pollutant, was performed at room temperature in an aqueous solution of titanium dioxide supported on cellulosic paper in the presence of an external UV lamp. The surface morphology of this photoactive tissue was characterized by SEM and FTIR. The performances of two geometric configurations were examined (batch reactor and annular recirculation reactor) in accordance with degradation and pollutant mineralization. The performance of the photocatalytic system was optimized by a parametric study to improve the impact of the different parameters on the efficiency of the degradation process, namely the initial concentration of the pollutant, the TiO2 cycle, the pH of the solution with the recirculating reactor, and the flow rate. The results showed 98% degradation of brilliant blue at the laboratory scale and 93.3% and 75% at the pilot flow rates of 800 and 200 L·h−1, respectively. The supported semiconductor showed good photodegradation ability during BB decomposition, showing that photocatalysis is a promising technique for water purification.

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