A submarine eruption started off the south coast of El Hierro, Canary Islands, on 10 October 2011 and continues at the time of this writing (February 2012). In the first days of the event, peculiar eruption products were found floating on the sea surface, drifting for long distances from the eruption site. These specimens, which have in the meantime been termed "restingolites" (after the close-by village of La Restinga), appeared as black volcanic "bombs" that exhibit cores of white and porous pumice-like material. Since their brief appearance, the nature and origin of these "floating stones" has been vigorously debated among researchers, with important implications for the interpretation of the hazard potential of the ongoing eruption. The "restingolites" have been proposed to be either (i) juvenile high-silica magma (e.g. rhyolite), (ii) remelted magmatic material (trachyte), (iii) altered volcanic rock, or (iv) reheated hyaloclastites or zeolite from the submarine slopes of El Hierro. Here, we provide evidence that supports yet a different conclusion. We have analysed the textures and compositions of representative "restingolites" and compared the results to previous work on similar rocks found in the Canary Islands. Based on their high-silica content, the lack of igneous trace element signatures, the presence of remnant quartz crystals, jasper fragments and carbonate as well as wollastonite (derived from thermal overprint of carbonate) and their relatively high oxygen isotope values, we conclude that "restingolites" are in fact xenoliths from pre-island sedimentary layers that were picked up and heated by the ascending magma, causing them to partially melt and vesiculate. As they are closely resembling pumice in appearance, but are xenolithic in origin, we refer to these rocks as "xeno-pumice". The El Hierro xeno-pumices hence represent messengers from depth that help us to understand the interaction between ascending magma and crustal lithologies beneath the Canary Islands as well as in similar Atlantic islands that rest on sediment-covered ocean crust (e.g. Cape Verdes, Azores). The occurrence of "restingolites" indicates that crustal recycling is a relevant process in ocean islands, too, but does not herald the arrival of potentially explosive high-silica magma in the active plumbing system beneath El Hierro
Understanding magma plumbing is essential for predicting the behaviour of explosive volcanoes. We investigate magma plumbing at the highly active Anak Krakatau volcano (Indonesia), situated on the rim of the 1883 Krakatau caldera by employing a suite of thermobarometric models. These include, clinopyroxene-melt thermobarometry, plagioclasemelt thermobarometry, clinopyroxene composition barometry and olivine-melt thermometry. Petrological studies have previously identified shallow magma storage in the region of 2-8 km beneath Krakatau, while existing seismic evidence points towards midto deep-crustal storage zone(s), at 9 and 22 km respectively. Our results show that clinopyroxene in Anak Krakatau lavas crystallized at a depth of 7-12 km, while plagioclase record both shallow crustal (3-7 km) and sub-Moho (23-28 km) levels of crystallisation. These magma storage regions coincide with well constrained major lithological boundaries in the crust, implying that magma ascent and storage at Anak Krakatau is strongly controlled by crustal properties. A tandem seismic tomography survey independently identified a separate upper crustal (< 7 km) and a lower to mid-crustal magma storage region (> 7 km). Both petrological and seismic methods are sensitive in detecting magma bodies in the crust, but suffer from various limitations. Combined geophysical and petrological surveys, in turn, offer increased potential for a comprehensive characterization of magma plumbing at active volcanic complexes.
Water is a key parameter in magma genesis, magma evolution, and resulting eruption styles, because it controls the density, the viscosity, as well as the melting and crystallization behavior of a melt. The parental water content of a magma is usually measured through melt inclusions in minerals such as olivine, a method which may be hampered, however, by the lack of melt inclusions suitable for analysis, or postentrapment changes in their water content. An alternative way to reconstruct the water content of a magma is to use nominally anhydrous minerals (NAMs), such as pyroxene, which take up low concentrations of hydrogen as a function of the magma's water content. During magma degassing and eruption, however, NAMs may dehydrate. We therefore tested a method to reconstruct the water contents of dehydrated clinopyroxene phenocrysts from the Western Canary islands (n 5 28) through rehydration experiments followed by infrared and M€ ossbauer spectroscopy. Employing currently available crystal/melt partitioning data, the results of the experiments were used to calculate parental water contents of 0.71 6 0.07 to 1.49 6 0.15 wt % H 2 O for Western Canary magmas during clinopyroxene crystallization at upper mantle conditions. This H 2 O range is in agreement with calculated water contents using plagioclase-liquid-hygrometry, and with previously published data for mafic lavas from the Canary Islands and comparable ocean island systems elsewhere. Utilizing NAMs in combination with hydrogen treatment can therefore serve as a proxy for pre-eruptive H 2 O contents, which we anticipate becoming a useful method applicable to mafic rocks where pyroxene is the main phenocryst phase.
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