Photocatalysis is one of the most promising technologies to achieve efficient carbon dioxide reduction reaction (CO2RR) under mild conditions. Herein, metalloporphyrin-based metal–organic frameworks (MOFs) with different metal centers, denoted as PCN-222, were utilized as visible-light photocatalysts for CO2 reduction. Due to the combination of the conjugated planar macrocyclic structures of metalloporphyrins and the stable porous structures of MOFs, all PCN-222 materials exhibited excellent light-harvesting and CO2-adsorbing abilities. Among the studied MOFs of varied metal centers (M = Pt, Fe, Cu, Zn, Mn), PCN-222(2H&Zn) exhibited the highest photocatalytic CO2RR performance, with an average CO yield of 3.92 μmol g−1 h−1 without any organic solvent or sacrificial agent. Furthermore, this was three and seven times higher than that of PCN-222(Zn) (1.36 μmol g−1 h−1) and PCN-222(2H) (0.557 μmol g−1 h−1). The superior photocatalytic activity of PCN-222(2H&Zn) was attributed to its effective photoexcited electron–hole separation and transportation compared with other PCN-222(2H&M) materials. The obtained results indicate that Zn ions in the porphyrin’s center played an important role in the reaction of active sites for the adsorption–activation of CO2. In addition, PCN-222(2H&Zn) showed the highest CO2 selectivity (almost 100%) and stability. This work provides a clear guide for the design of efficient photocatalysts.
The design and performance of the inner detector trigger for the high level trigger of the ATLAS experiment at the Large Hadron Collider during the 2016–2018 data taking period is discussed. In 2016, 2017, and 2018 the ATLAS detector recorded $$35.6~\mathrm {fb}^{-1}$$
35.6
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, $$46.9~\mathrm {fb}^{-1}$$
46.9
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, and $$60.6~\mathrm {fb}^{-1}$$
60.6
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1
respectively of proton–proton collision data at a centre-of-mass energy of 13 TeV. In order to deal with the very high interaction multiplicities per bunch crossing expected with the 13 TeV collisions the inner detector trigger was redesigned during the long shutdown of the Large Hadron Collider from 2013 until 2015. An overview of these developments is provided and the performance of the tracking in the trigger for the muon, electron, tau and b-jet signatures is discussed. The high performance of the inner detector trigger with these extreme interaction multiplicities demonstrates how the inner detector tracking continues to lie at the heart of the trigger performance and is essential in enabling the ATLAS physics programme.
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