Charge transport in disordered organic semiconductors, which is governed by incoherent hopping between localized molecular states, is frequently studied using a mean-field approach. However, such an approach only considers the time-averaged occupation of sites and neglects the correlation effect resulting from the Coulomb interaction between charge carriers. Here, we study the charge transport in unipolar organic devices using kinetic Monte Carlo simulations and show that the effect of Coulomb correlation is already important when the charge-carrier concentration is above 10 −3 per molecular site and the electric field is smaller than 10 8 V/m. The mean-field approach is then no longer valid, and neglecting the effect can result in significant errors in device modeling. This finding is supported by experimental current density-voltage characteristics of ultrathin sandwich-type unipolar poly(3-hexylthiophene) (P3HT) devices, where high carrier concentrations are reached.

Electrowetting on dielectrics is a fascinating as well as a precise way in microfluid manipulation. As one of the controversial conclusions, charge trapping on the dielectric surface might be one of the causes which induces water contact angle saturation and forms one of the significant issues that bear on the applications of electrowetting on dielectrics. Recently, it was demonstrated that the contact angle saturation can be significantly reduced by employing an oil lubrication layer on the hydrophobic surface. In this work, we have investigated the influence of effects of an oil layer on the electrowetting behavior by dissolving a nonpolar oil-soluble dye in the oil phase. We monitored the contact angle of water drops with varying pH on an oil-lubricated hydrophobic insulator. Interestingly, we found asymmetry in the electrowetting curve. Several analysis methods were proceeded trying to explain this asymmetric electrowetting phenomenon. First and foremost, the electrochemical properties of dye were investigated by cyclic voltammetry which demonstrates that oxidation-reduction reactions of the dye can indeed happen on the electrode and one irreversible peak was found which indicated that the dye molecule might decompose at a higher voltage. Second, thin-layer cyclic voltammetry confirmed ions can transgress the oil/water interface. Also, the conductivity of the oil phase increases with the dissolved dye concentration, which indicates that charges can be transported in the oil phase. Finally, to further understand the transfer mechanism, the transient current of dye-doped oil was measured, which indicates that the formation of inverse micelles in the oil phase at high voltage could be one of the charge carriers. We demonstrated the oil-property-dependent asymmetry phenomenon of electrowetting and its association with charge transfer through the oil/water interface for the first time.

We report charge transport measurements in nanoscale vertical pillar structures incorporating ultrathin layers of the organic semiconductor poly(3-hexylthiophene) (P3HT). P3HT layers with thickness down to 5 nm are gently top-contacted using wedging transfer, yielding highly reproducible, robust nanoscale junctions carrying high current densities (up to 106 A/m2). Current-voltage data modeling demonstrates excellent hole injection. This work opens up the pathway towards nanoscale, ultrashort-channel organic transistors for high-frequency and high-current-density operation.

A pixel in an electrowetting display (EWD) can be viewed as a confined water/oil two-phase microfluidic system that can be manipulated by applying an electric field. The phenomenon of charge trapping in the protective dielectric and conductivity of the oil phase reduce the effective electric field that is required to keep the three-phase contact line (TCL) in place. This probably leads to an oil-backflow effect which deteriorates the electro-optical performance of EWD devices. In order to investigate charge trapping and conduction effects on the device electro-optical response, an EWD device was studied, which was fabricated with a black oil, aiming for a high-contrast ratio and color-filter display. For comparison, we also prepared a device containing a purple oil, which had a lower electrical conductivity. As anticipated, the black-oil device showed faster backflow than the purple-oil device. A simple model was proposed to explain the role of oil conductivity in the backflow effect. In addition, the rebound and reopening effects were also observed after the voltage was switched to zero. The above observations were strongly dependent on polarity. By combining observations of the polarity dependence of the oil conductivity and assuming that negative charges trap more strongly in the dielectric than positive charges, our experimental results on rebound and reopening can be explained. In the AC optical response, the pixel closing speed decreased in time for intermediate frequencies. This is likely related to the phenomenon of charge trapping. It was also found that the periodic driving method could not suppress the backflow effect when the driving frequency was above ~10 kHz. Our findings confirm the significance of the above charge-related effects of EWD devices, which need to be investigated further for better understanding in order to properly design/use materials and driving schemes to suppress them.