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In the present work the process of hydrogen production was conducted in the plasma-catalytic reactor, the substrates were first treated with plasma and then introduced into the catalyst bed. Plasma was produced by a spark discharge. The discharge power ranged from 15 to 46 W. The catalyst was metallic nickel supported on Al2O3. The catalyst was active from a temperature of 400 °C. The substrate flow rate was 1 mol/h of water and 1 mol/h of methanol. The process generated H2, CO, CO2 and CH4. The gas which formed the greatest amount was H2. Its concentration in the gas was ~60%. The conversion of methanol and the production of hydrogen in the plasma-catalytic reactor were higher than in the plasma and catalytic reactors. The synergy effect of the interaction of two environments, i.e., plasma and the catalyst, was observed. The highest hydrogen production was 1.38 mol/h and the highest methanol conversion was 64%. The increased in the discharge power resulted in increasing methanol conversion and hydrogen production.

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This study concerns the production of hydrogen from a mixture of ethanol and water. The process was conducted in plasma generated by a spark discharge. The substrates were introduced in the liquid phase into the reactor. The gaseous products formed in the spark reactor were hydrogen, carbon monoxide, carbon dioxide, methane, acetylene, and ethylene. Coke was also produced. The energy efficiency of hydrogen production was 27 mol(H2)/kWh, and it was 36% of the theoretical energy efficiency. The high value of the energy efficiency of hydrogen production was obtained with relatively high ethanol conversion (63%). In the spark discharge, it was possible to conduct the process under conditions in which the ethanol conversion reached 95%. However, this entailed higher energy consumption and reduced the energy efficiency of hydrogen production to 8.8 mol(H2)/kWh. Hydrogen production increased with increasing discharge power and feed stream. However, the hydrogen concentration was very high under all tested conditions and ranged from 57.5 to 61.5%. This means that the spark reactor is a device that can feed fuel cells, the power load of which can fluctuate.