As one of the biggest cities in North China, Jinan has been suffering heavy air pollution in recent decades. To better characterize the ambient particulate matter in Jinan during heavy pollution periods, we collected daily PM2.5 (particulate matter with aerodynamic diameters equal to or less than 2.5 μm) filter samples from 15 October 2017 to 31 January 2018 and analyzed their chemical compositions (including inorganic water-soluble ions (WSIs), carbonaceous species, and inorganic elements). The daily average concentration of PM2.5 was 83.5 μg/m3 during the sampling period. A meteorological analysis revealed that both low wind speed and high relative humidity facilitated the occurrence of high PM2.5 pollution episodes. A chemical analysis indicated that high concentrations of water-soluble ions, carbonaceous species, and elements were observed during heavy pollution days. The major constituents of PM2.5 in Jinan were secondary aerosol particles and organic matter based on the results of mass closure. Chemical Mass Balance (CMB) was used to track possible sources and identified that nitrate, sulfate, vehicle exhaust and coal fly ash were the main contributors to PM2.5 during heavy pollution days in Jinan, accounting for 25.4%, 18.6%, 18.2%, and 13.3%, respectively.
Abstract. Volatile organic compounds (VOCs) have a wide range of sources and have a significant impact on the ecological environment and human health, which have attracted wide attention of many researchers. In this paper, the pollution characteristics of VOCs, the role of VOCs in atmospheric chemistry including OH reaction reactivity (LOH), Ozone Formation Potential (OFP) and SOA generation potential (SOAP), VOCs source apportionment were discussed and reviewed.
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