The rheological properties and time effect of a quaternary ammonium salt gemini surfactant Cn‐s‐Cn•2Br solution were measured. The rheological properties were markedly different at various concentrations of the surfactant C12‐2‐C12•2Br solutions. When the alkyl chain of Cn‐2‐Cn•2Br solution is 14 or 16, the rheological properties of the solution exhibit fluid dilatancy very similar to C12‐2‐C12•2Br solutions. However, when the length of the spacer is four or six, C12‐s‐C12•2Br solutions exhibit Newtonian fluid behavior and are quite different from the C12‐2‐C12•2Br solution. A C12‐2‐C12•2Br solution at a high concentration shows negative thixotropy and time dependency.
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