129ChemInform Abstract Vinyl triflates such as (I) undergo Pd(0)-catalyzed cross-coupling reaction with the stannane (II) to yield dienes such as (III) which are hydrolyzed to give α,β-unsaturated ketones such as (IV). The analogous procedure with phenyl triflate (V) results n the formation of acetophenone (VI). In the presence of carbon monoxide (VII), ethoxyvinyl ketones (VIII) are obtained which are hydrolyzed to give the α-diketones (IX). Numerous further examples are given in the original paper.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.