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In contrast to predominantly hydrocarbon-rich natural gases in the western part of the Central European Basin (CEB), accumulations of natural gases from the eastern part of the North German Basin (NGB) are nitrogen-rich with up to 90% N 2 . This study is focused on the behaviour of fixed ammonium in clay minerals of organic-rich Palaeozoic sediments in the eastern part of the NGB as a major source of nitrogen-rich natural gases. Carboniferous shales have been investigated for a better understanding of nitrogen fixing during diagenesis, storage during burial and release during devolatilization processes or fluid-rock interactions. The total nitrogen contents in the studied Carboniferous shales of the NGB reach up to 2700 ppm with an inorganic fixed portion (in the form of NH 4 + -N) of more than 60%. The results of this study indicate an increasing proportion of the mineralogically fixed ammonium with increasing thermal maturity and storage up to catagenetic conditions. The isotopic composition of fixed-NH 4 is relatively homogeneous in the majority of the shales and ranges from +1 to +3.5&. In contrast, samples from the basin centre show a significant decrease in ammonium contents down to 460 ppm coupled with a shift in d 15 N up to +5.6& suggesting a release of nitrogen on a large scale. Calculation of nitrogen loss and isotopic fractionation indicate that more than 30% of nitrogen was released as ammonium probably as a consequence of fluid-rock interaction with highly saline brines.

The geochemistry of carbonate fault rocks has been examined in two areas of the Arava Fault segment, which forms the major branch of the Dead Sea Transform between the Dead Sea and the Gulf of Aquaba. The role of fluids in faulting deformation in the selected fault segment is remarkably different from observations at other major fault zones. Our data suggest reduced fluid rock interactions in both areas and limited fluid flow. The fault did not act as an important fluid conduit. There are no indications that hydrothermal reactions (cementation, dissolution) did change the strength and behavior of the fault zone, although the two areas show considerable differences with respect to fluid sources and fluid flow. In one area, the investigated calcite mineralization reveals an open fluid system with fluids originating from a variety of sources. Stable isotopes (d 13 C, d 18 O), strontium isotopes, and trace elements indicate both infiltration of descending (meteoric and/or sea water) and ascending hydrothermal fluids. In the other area, all geochemical data indicate only local (small scale) fluid redistribution. These fluids were derived from the adjacent limestones under nearly closed-system conditions.