The effect of up to 0.5 mass% C on a steel with 18 to 19 mass% Cr and Mn each and about 0.6 mass% N was investigated by tensile tests, notch impact tests and corrosion tests. The experimental results show that the solution anneal temperature and the sensitisation to intercrystalline corrosion depend on the carbon content which raise the strength and cold work hardening. Up to 1 mass% CþN the ductile to brittle transition temperature remains at about À90 8C. Corrosion in diluted aqueous solutions of H 2 SO 4 , HCl and NaCl is described.
The detection of structural changes in time series from industrial processes monitoring is of great interest. We investigate the limits and possibilities of two recently developed methods, one for the off-line detection of changed volatilities [Wied et al., 2011] and one for the on-line detection of changes in the course of the time series [Borowski and Fried, 2011]. The investigation is carried out on several time series from thermal spraying processes. The processes are deliberately manipulated to produce structural changes at known time points.
Joint alloying of 0.85 to 1.1 mass% C + N raises the strength and cold work hardening of steels with 18 to 19 mass% Cr and Mn each and allows to produce them at atmospheric pressure. A yield strength of 600 MPa is combined with a true fracture stress of almost 2500 MPa and ≈ 70 % elongation. However, there is a risk of carbide/nitride precipitation during quenching of thicker cross sections after solution annealing. The addition of Mo and Cu affects the corrosion resistance as well as the precipitation. Submersion test and current density/potential tests in several aqueous solutions characterize the corrosion behaviour. Tests on intercrystalline corrosion are used to detect the precipitation as a function of quenching rate. It is shown that the C/N ratio is of key importance in improving the properties.
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