Purpose
T-spline is the latest powerful modeling tool in the field of computer-aided design. It has all the merits of non-uniform rational B-spline (NURBS) whilst resolving some flaws in it. This work applies T-spline surfaces to additive manufacturing (AM). Most current AM products are based on Stereolithograph models. It is a kind of discrete polyhedron model with huge amounts of data and some inherent defects. T-spline offers a better choice for the design and manufacture of complex models.
Design/methodology/approach
In this paper, a direct slicing algorithm of T-spline surfaces for AM is proposed. Initially, a T-spline surface is designed in commercial software and saved as a T-spline mesh file. Then, a numerical method is used to directly calculate all the slicing points on the surface. To achieve higher manufacturing efficiency, an adaptive slicing algorithm is applied according to the geometrical properties of the T-spline surface.
Findings
Experimental results indicate that this algorithm is effective and reliable. The quality of AM can be enhanced at both the designing and slicing stages.
Originality/value
The T-spline and direct slicing algorithm discussed here will be a powerful supplement to current technologies in AM.
Organic co-crystal engineering is a promising method to make multifunctional materials. Here, the marriage of macrocyclic chemistry and co-crystal engineering provides a smart strategy to build vapochromic materials. The macrocycle co-crystals (MCCs) were constructed from p-electron rich pillar[5]arene (P5) and an electron-deficient pyromellitic diimide derivative (PDI) on a 10 g scale. MCCs of P5-PDI are in red owing to the formation of a charge-transfer (CT) complex. After solvent removal, a white crystalline solid with a new structure (P5-PDIa) is yielded, which exhibits selective vapochromic responses to volatile organic compounds (VOCs) of haloalkanes, accompanied by color changes from white to red or orange. Powder and single-crystal X-ray diffraction analyses reveal that the color changes are attributed to the vapor-triggered solid-state structural transformation to form CT co-crystals. Coating films of P5 and PDI on glass showed a visible vapochromic behavior with good reversibility. Scheme 1. Chemical structures of a) co-crystal composition of P5 and PDI, b) haloalkane molecules, and c) other selected VOCs.
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