The electron-injection energy losses of dye-sensitized solar cells (DSSCs) are among the fundamental problems hindering their successful breakthrough application. Two triazatruxene (TAT)-based sensitizers, with one containing a flexible Z-type double bond and another a rigid single bond, coded as ZL001 and ZL003, respectively, have been synthesized and applied in DSSCs to probe the energy losses in the process of electron injection. Using time-resolved laser spectroscopic techniques in the kinetic study, ZL003 with the rigid single bond promotes much faster electron injection into the conductive band of TiO2 especially in the locally excited state (hot injection), which leads to higher electron density in TiO2 and a higher V oc. The devices based on ZL003 exhibited a champion power conversion efficiency (PCE) of 13.6% with V oc = 956 mV, J sc = 20.73 mA cm–2, and FF = 68.5%, which are among the highest recorded results to date on single dye-sensitized DSSCs. An independent certified PCE of 12.4% has been obtained for devices based on ZL003.

The first clinical MR-IGRT system was validated for real-time tracking and gating capabilities and shown to be reliable and accurate. Patient workflow methods were developed for efficient treatment. Periodic quality assurance tests can be efficiently performed with commercially available equipment to ensure accurate system performance.

Massive multiple-input multiple-output (MIMO) with frequency division duplex (FDD) mode is a promising approach to increasing system capacity and link robustness for the fifth generation (5G) wireless cellular systems. The premise of these advantages is the accurate downlink channel state information (CSI) fed back from user equipment. However, conventional feedback methods have difficulties in reducing feedback overhead due to significant amount of base station (BS) antennas in massive MIMO systems. Recently, deep learning (DL)-based CSI feedback conquers many difficulties, yet still shows insufficiency to decrease the occupation of uplink bandwidth resources. In this paper, to solve this issue, we combine DL and superimposed coding (SC) for CSI feedback, in which the downlink CSI is spread and then superimposed on uplink user data sequences (UL-US) toward the BS. Then, a multi-task neural network (NN) architecture is proposed at BS to recover the downlink CSI and UL-US by unfolding two iterations of the minimum mean-squared error (MMSE) criterion-based interference reduction. In addition, for a network training, a subnet-by-subnet approach is exploited to facilitate the parameter tuning and expedite the convergence rate. Compared with standalone SC-based CSI scheme, our multi-task NN, trained in a specific signal-to-noise ratio (SNR) and power proportional coefficient (PPC), consistently improves the estimation of downlink CSI with similar or better UL-US detection under SNR and PPC varying. INDEX TERMS Channel state information (CSI), deep learning (DL), superimposed coding (SC), feedback, massive multiple-input multiple-output (MIMO).

COP1 (CONSTITUTIVE PHOTOMORPHOGENIC 1), a ubiquitin E3 ligase, is a central negative regulator of photomorphogenesis. However, how COP1 activity is regulated by post-translational modifications remains largely unknown. Here we show that SUMO (small ubiquitin-like modifier) modification enhances COP1 activity. Loss-of-function siz1 mutant seedlings exhibit a weak constitutive photomorphogenic phenotype. SIZ1 physically interacts with COP1 and mediates the sumoylation of COP1. A K193R substitution in COP1 blocks its SUMO modification and reduces COP1 activity in vitro and in planta. Consistently, COP1 activity is reduced in siz1 and the level of HY5, a COP1 target protein, is increased in siz1. Sumoylated COP1 may exhibits higher transubiquitination activity than does non-sumoylated COP1, but SIZ1-mediated SUMO modification does not affect COP1 dimerization, COP1-HY5 interaction, and nuclear accumulation of COP1. Interestingly, prolonged light exposure reduces the sumoylation level of COP1, and COP1 mediates the ubiquitination and degradation of SIZ1. These regulatory mechanisms may maintain the homeostasis of COP1 activity, ensuing proper photomorphogenic development in changing light environment. Our genetic and biochemical studies identify a function for SIZ1 in photomorphogenesis and reveal a novel SUMO-regulated ubiquitin ligase, COP1, in plants.

In a frequency division duplex (FDD) massive multiple input multiple output (MIMO) system, the channel state information (CSI) feedback causes a significant bandwidth resource occupation. In order to save the uplink bandwidth resources, a 1-bit compressed sensing (CS)-based CSI feedback method assisted by superimposed coding (SC) is proposed. Using 1-bit CS and SC techniques, the compressed support-set information and downlink CSI (DL-CSI) are superimposed on the uplink user data sequence (UL-US) and fed back to base station (BS). Compared with the SC-based feedback, the analysis and simulation results show that the UL-US's bit error ratio (BER) and the DL-CSI's accuracy can be improved in the proposed method, without using the exclusive uplink bandwidth resources to feed DL-CSI back to BS.

Perovskite solar cells (PSCs) has skyrocketed in the past decade to an unprecedented level due to their outstanding photoelectric properties and facile processability. However, the utilization of expensive hole transport materials (HTMs) and the inevitable instability instigated by the deliquescent dopants represent major concerns hindering further commercialization. Here, a series of low-cost, conjugated polymers are designed and applied as dopantfree HTMs in PSCs, featuring tuned energy levels, good temperature and humidity resistivity, and excellent photoelectric properties. Further studies highlight the critical and multifaceted roles of the polymers with respect to facilitating charge separation, passivating the surface trap sites of perovskite materials, and guaranteeing long-term stability of the devices. A stabilized power conversion efficiency (PCE) of 20.3% and remarkably enhanced device longevity are achieved using the dopant-free polymer P3 with a low concentration of 5 mg/mL, qualifying the device as one of the best PSC systems constructed on the basis of dopant-free HTMs so far. In addition, the flexible PSCs based on P3 also exhibit a PCE of 16.2%. This work demonstrates a promising route toward commercially viable, stable, and efficient PSCs.

MRIgRT is widely applicable within the field of radiation oncology and new clinical uses continue to emerge. At our institution to date, applications such as ART for gastrointestinal cancers and accelerated partial breast irradiation (APBI) for breast cancer have become dominant indications, although this is likely to continue to evolve.

Abstract2D Ruddlesden–Popper perovskites (RPPs) have emerged as a promising solar cell material. A group of novel RPPs with cyclohexane methylamine (CMA) as a spacer cation is presented. Unlike previously reported RPPs, the deposited films of (CMA)2(MA)n−1PbnI3n+1 (MA is CH3NH3+, n = 1, 2, 3, …) exhibit multiple phases with reverse‐graded quantum well (QW) distribution; small n (n = 2) RPPs are located at the surface and large n (n ≥ 10) RPPs at the bottom. This has three advantages: (a) The outer, more moisture resistant, small n RPPs create a stable barrier that protects the vulnerable large n RPP lattice from being attacked by water molecules. (b) It forms a type‐II band alignment between different phases, which favors self‐driven charge transport. (c) The natural structure of graded QWs expands the range of photon collection. Attributed to these properties, the best efficiency of 15.05%, with high open‐circuit voltage (Voc) of 1.10 V for a first‐generation solar cell containing (CMA)2(MA)8Pb9I28, is achieved. A notable enhancement in short wavelength is observed in the Incident photon‐to‐current conversion efficiency spectra. This device shows significantly improved long‐term stability, retaining ≈95% of the initial efficiency after 4600 h exposure in ambient conditions with 40–70% relative humidity.