In this study, a pore-scale simulation method is applied to quantitatively study the variation of solute dilution through porous media with different cementation degrees and explore the corresponding mechanisms. The study results indicated that the cementation degrees of the solid grains had a significant effect on the solute dilution process and that the influence was very complicated. The complexity was manifested in that the effect of rising cementation degree on the solute dilution process would be different or even completely opposite in the porous media in which the solid grains cement slightly with that in porous media with a higher cementation degree. For example, for the porous media in which the solid grains were slightly cemented (the percentage of the cemented solid grains P c is less than 40%), the dilution effects became enhanced with the increase of cementation degree. Then, after P c increased to about 55%, the dilution effect was obviously weakened, and the solute was in an incomplete dilution state for a long period of time. In addition, this study found that the properties of the flow fields may vary greatly in porous media with different cementation degrees and that those differences in the flow fields resulted in the distinct behavior of the solute dilution. It is interesting to note that a more heterogeneous flow field had not necessarily led to the enhancement of the dilution process.
Surface water and groundwater (SW-GW) are an inseparable whole, having a tightly coupled hydraulic relationship and frequent inter-transformation. As such, the quantitative calculation of water exchange between SW-GW is a difficult challenge. To address this issue, we propose the use of a physically based and distributed hydrological model, called WEP-L, in order to analyze the effects of the SW-GW interaction and its spatiotemporal variation characteristics in the Xiaoqing River basin. We demonstrate that the SW-GW interaction is significantly affected by season. The simulated annual average exchange volume of SW-GW above the control section of Huangtaiqiao Station from 1980 to 2020 is found to be 54.79 m3/s. The exchange volumes of SW-GW in the wet and dry season are 28.69 m3/s and 13.46 m3/s, respectively, accounting for 48.75% and 22.87% of the whole year. In addition, considering two types of climate change scenarios, the exchange capacity of SW-GW increases by 0.42m3/s when the rainfall increases by 5%, while the exchange capacity decreases by only 0.2 m3/s when the temperature increases by 0.2 °C. This study provides insights for the quantification of the SW-GW interaction at the regional scale, which will benefit our understanding of the water cycle and evolution of water resources in Xiaoqing River basin.
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