The origins of the usage of different substances in beauty, skin, body, hair, and nails care products can be found in ancient times. To achieve better quality and enhance their effects, some additives such as preservatives, stabilizers, mineral pigments, dye, and shine were added to these products. Some of these substances may also have allergic, irritating, and harmful effects on human health. The aim of this study was the optimization of the potentiometric stripping analysis (PSA) for the purpose of determining the content of heavy metals (lead, cadmium, zinc), in some commercial cosmetic beauty products (lipsticks, lip glosses, eye shadows, and henna hair dye). In addition, in order to monitor the potential adverse effects of henna dye on hair quality, as well as the total body burden of heavy metals (Pb, Cd), the paper analyzed hair samples before and after henna dye treatment. Beauty products used for cosmetic purposes can have adverse effects to human health due to the fact that they contain lead, a highly toxic metal. The lead content in the tested samples varied depending on the additives used along with the method of production. The cosmetic products that were analyzed in this study contained a certain amount of zinc, which is an essential element, although its content above the prescribed limit may lead to side effects. Highly toxic metal, cadmium, was not detected in the tested samples. The presence of these metals in cosmetic products certainly indicate that it is necessary to monitor and determinate the content of toxic heavy metals in these products, especially because they are in direct contact with skin or mucous membranes and are often used in daily life.

German Society for Horticultural Science Abbreviations CV cyclic voltammetry ABTS 2,2'-azinobis-3-ethylbenzothiazoline-6-sulfonate DPPH 2-diphenyl-2-picrylhydrazyl hydrate FRAP ferric reducing-antioxidant power RP reduction power Fe(III) to Fe(II) Trolox 6-hydroxy-2,5,7,8-tetramethylchroman-2carboxylic acid TPTZ 2,4,6-tri(2-pyridyl)-S-tirazine AEAC Ascorbate Equivalent Antioxidant Capacity TEAC Trolox Equivalent Antioxidant Capacity ACI Antioxidant Composite Index

-Introduction.Among different fruit species, aronia have attracted a great attention because of its wide range of protective effects with potential benefits for human health. Furthermore, the consumption of products of aronia (juice, tea, berries) is becoming a part of a healthy lifestyle. Materials and Methods. The multi-element characterization of products of aronia has been carried out using inductively coupled plasma atomic emission spectrometry (ICP-AES). Results and Discussion. Among the major elements, the most abundant are K, Ca and P, followed by the Mg and Na. Fe, Zn, Mn, Cu, Bi and Si are the most abundant among the microelements. In terms of heavy metals (As, Cd, Pb), it can be concluded that the concentrations of them are below permissible levels (PLs) prescribed by national legislation in all samples. The chemometric techniques of principal component analysis (PCA) and cluster analysis (CA) were used to differentiation of products aronia according to their metal content. The application of PCA and CA was resulted in two clusters with similarities in the mineral composition. The first cluster includes tea bag samples (T1-T6). The second cluster includes berries (B1, B2), juices (J1-J4) and leaves (L). Conclusion. Data obtained in this study showed that analyzed products are potentially a rich source of some dietary metals such are K, Ca, P, Mg, Na, Fe and Zn. Obtained results could be also used as selection criteria for further use of products of aronia as a part of conventional diet.

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Heavy metals are highly toxic to living organisms even in low concentrations owing to their cumulative effect. In this study the overall content of lead in herbal drugs was determined, as well as the content of lead which was released from tested drugs during the preparation of tea drinks. To determine the content of toxic lead, the highly sensitive microanalytical technique of the potentiometric stripping analysis (PSA) with oxygen as the oxidant was used. The lowest overall content of lead was detected for chamomile and ranged from 0.73 to 0.77 µg/g, while the greatest content of lead was determined in the samples of the frangula bark, and yielded approximately 3 µg/g. The lead content in the prepared tea drinks ranged from 0.26 to 1.23 µg/g and depended on the manner in which tea drink was prepared. All of the herbal drugs in this study contain a certain amount of the toxic metal lead, but at the same time, the contents were below the levels prescribed for this metal. The content of lead released from the herbal drug into the tea drink was three to five times lower than those of the overall content of this metal.