Boron nitride (BN) presented enormous potential in the fabrication of novel membranes with superior separation efficiency. Researchers try to produce membranes with high solvent permeability and good rejection performance in industrial applications. In this review, the recent progress in the fabrication of BN-based membranes with different fabrication techniques and various applications is reviewed. Representative studies on applying BN-based membranes in gas separation, proton exchange, electrodialysis, and water filtration membranes to develop their performance and stability, induce antifouling characteristics, and decline the trade-off between selectivity and permeability, together with the explanation of their mechanisms, are discussed. Moreover, various methods of synthesis of BN allotropes are introduced. In addition, a brief review of simulation studies (molecular dynamic and density function theory) on theoretical studies of BN nanosheet membranes was performed. The authors hope that this review will arouse the active interest of many researchers in the further development of the BNs application in membrane science and technology.
Present work investigates platinum uptake from synthetically prepared, dilute platinum-bearing solutions using biomass residues, i.e. pistachio nut shell and rice husk, which are abundant in Turkey, and provides a comparison between these two biosorbents. Effects of the different uptake parameters, sorbent dosage, contact time, temperature and pH of solution on platinum uptake (%) were studied in detail on a batch sorption. Before the pistachio nut shell was activated, platinum uptake (%) was poor compared to the rice husk. However, after the pistachio nut shell was activated at 1000 °C under an argon atmosphere, the platinum uptake (%) increased two-fold. The pistachio nut shell (original and activated) and rice husk were shown to be better than commercially available activated carbon in terms of adsorption capacity. These two sorbents have also been characterized by FTIR and SEM. Adsorption equilibrium data best complied with the Langmuir isotherm model. Maximum adsorption capacities, Q max , at 25 °C were found to be 38.31 and 42.02 mg.g -1 for the activated pistachio nut shell and rice husk, respectively. Thermodynamic calculations using the measured ∆H°, ∆S° and ∆G° values indicate that the uptake process was spontaneous and endothermic. The experimental data were shown to be fit the pseudo-second-order kinetic model.
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