Organic light‐emitting diodes (OLEDs) are efficient large‐area light sources facing their market entry. Still, the development of stable and more efficient blue emitters and the enhancement of light outcoupling remain challenges for further device improvements. Here, we review the working principles of OLEDs and highlight ongoing efforts to improve their efficiency, in particular by coupling out more light.

Organic light-emitting diodes (OLEDs) are promising new large-area light sources on their way to commercialization. However, there is still much room for improvement in terms of device efficiency and long-term stability under electrical operation. In this article, we review the current issue of efficiency analysis based on optical simulations of state-of-the-art OLED stacks. In detail, we present a method to determine the radiative quantum efficiency of the emitter, figure out the crucial points for non-isotropic emitter orientation and discuss the application of the developed method to analyze degradation effects during electrical operation.

The efficiency of organic light-emitting diodes (OLEDs) is still limited by poor light outcoupling. In particular, the excitation of surface plasmon polaritons (SPPs) at metal-organic interfaces represents a major loss channel. By combining optical simulations and experiments on simplified luminescent thin-film structures we elaborate the conditions for the extraction of SPPs via coupling to high-index media. As a proof-of-concept, we demonstrate the possibility to extract light from wave-guided modes and surface plasmons in a top-emitting white OLED by a high-index prism.

We present a method to achieve a consistent, comprehensive efficiency analysis of fluorescent organic light-emitting diodes (OLEDs) showing non-isotropic emitter orientation and triplet-to-singlet up-conversion. Combining photoluminescence lifetime and external quantum efficiency measurements on OLEDs with varying cavity length allows for an independent determination of the radiative emitter efficiency under optical as well as electrical excitation. The difference clearly shows a significant enhancement of the singlet exciton fraction to more than 25% under electrical operation. Furthermore, the presented method does not require detailed information about the emitting system and is generally applicable for a comprehensive efficiency analysis of bottom-emitting OLEDs

The efficiency of organic light-emitting diodes (OLEDs) is limited since only a small fraction of the consumed electrical power is converted into visible light that is finally extracted to air. Most of the efficiency loss is caused by suboptimal radiative quantum efficiency (RQE) of the emitting guest-host system and by dissipating a huge part of the radiated energy to optical modes such as surface plasmons or waveguided modes, which cannot easily be extracted by common outcoupling structures. In order to increase the external quantum efficiency (EQE) of OLEDs new approaches are needed. Recent studies show that the EQE can be enhanced considerably by horizontally oriented emitters, a feature that is well known for fluorescent emitters and has lately been demonstrated in phosphorescent state-of-the-art OLEDs. By means of optical simulations we investigated the influence of non-isotropic emitter orientation on the effective RQE and the outcoupling factor. We show that in order to achieve a consistent efficiency analysis it is indispensable to account for possible deviations from isotropy. Ignoring these orientation effects leads to significant misinterpretation of the RQE and other factors, which determine the external quantum efficiency of a device. Furthermore, we demonstrate the huge potential for efficiency enhancement of mainly parallel dipole emitter orientation in both fluorescent and phosphorescent OLEDs