CO2‐Reduktion Harnstoffgruppen in einem Eisenporphyrinkatalysator führen zu einer mehrfachen Stabilisierung von CO2 durch Wasserstoffbrücken. Wie Z. Halime, A. Aukauloo et al. in ihrer Zuschrift auf S. 4552 zeigen, hat der Katalysator eine hohe Aktivität in der CO2‐Reduktion.
In this study we report a strategy to attach methylimidazolium fragments as ionic liquid units on an established iron porphyrin catalyst for the selective reduction of CO2 to CO in water, precluding the need for external proton source.
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