The Wiedemann-Franz (WF) law establishes a link between heat and charge transport due to electrons in solids. The extent of its validity in presence of inelastic scattering is a question raised in different contexts. We report on a study of the electrical, σ, and thermal, κ, conductivities in WP2 single crystals. The WF holds at 2 K, but a downward deviation rapidly emerges upon warming. At 13 K, there is an exceptionally large mismatch between Lorenz number and the Sommerfeld value.We show that this is driven by a fivefold discrepancy between the T -square prefactors of electrical and thermal resistivities, both caused by electron-electron scattering. This implies the existence of abundant small-scattering-angle collisions between electrons, due to strong screening. By quantifying the relative frequency of collisions conserving momentum flux, but degrading heat flux, we identify a narrow temperature window where the hierarchy of scattering times may correspond to the hydrodynamic regime.
We report on a study of electric resistivity and magnetic susceptibility measurements in electron irradiated SrTi0.987Nb0.013O3 single crystals. Point-like defects, induced by electron irradiation, lead to an almost threefold enhancement of the residual resistivity, but barely affect the superconducting critical temperature (Tc). The pertinence of Anderson's theorem provides strong evidence for a s-wave superconducting order parameter. Stronger scattering leads to a reduction of the effective coherence length (ξ) and the deduced coherence length in the clean limit (ξ0) is around the BCS coherence length (ξBCS). Combined with thermal conductivity data pointing to multiple nodeless gaps, the current results identify optimally doped SrTi1−xNbxO3 as a multi-band s-wave superconductor.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.